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Vapour sensing properties of graphene-covered gold nanoparticles.

ABSTRACT: We investigated the vapour sensing properties of different graphene-gold hybrid nanostructures. We observed the shifts in the optical spectra near the local surface plasmon resonance of the gold nanoparticles by changing the concentration and nature of the analytes (ethanol, 2-propanol, and toluene). The smaller, dome-like gold nanoparticles proved to be more sensitive to these vapours compared to slightly larger, flat nanoparticles. We investigated how the optical response of the gold nanoparticles can be tuned with a corrugated graphene overlayer. We showed that the presence of graphene increased the sensitivity to ethanol and 2-propanol, while it decreased it towards toluene exposure (at concentrations ≥ 30%). The slope changes observed on the optical response curves were discussed in the framework of capillary condensation. These results can have potential impact on the development of new sensors based on graphene-gold hybrids.

SUBMITTER: Piszter G

PROVIDER: S-EPMC9417911 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Vapour sensing properties of graphene-covered gold nanoparticles.

Piszter Gábor G Kertész Krisztián K Molnár György G Pálinkás András A Deák András A Osváth Zoltán Z

Nanoscale advances 20190517 6

We investigated the vapour sensing properties of different graphene-gold hybrid nanostructures. We observed the shifts in the optical spectra near the local surface plasmon resonance of the gold nanoparticles by changing the concentration and nature of the analytes (ethanol, 2-propanol, and toluene). The smaller, dome-like gold nanoparticles proved to be more sensitive to these vapours compared to slightly larger, flat nanoparticles. We investigated how the optical response of the gold nanoparti ...[more]

PMID: 36131993

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