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[(1,2,5,6-η)-Cyclo-octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl-idene)(tri-cyclo-hexyl-phosphane-κP)iridium(I) tetra-fluorido-borate di-chloro-methane monosolvate.

ABSTRACT: The title compound, [Ir(C₈H₁₂)(C₆H₁₁N₃)(C₁₈H₃₃P)]BF₄·CH₂Cl₂, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra-fluorido-borate counter-anion, crystallizes with one di-chloro-methane solvent mol-ecule per formula unit. The Ir^I atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tri-cyclo-hexyl-phosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units.

SUBMITTER: Rushlow J

PROVIDER: S-EPMC9635413 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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[(1,2,5,6-η)-Cyclo-octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl-idene)(tri-cyclo-hexyl-phosphane-κP)iridium(I) tetra-fluorido-borate di-chloro-methane monosolvate.

Rushlow Joshua J Astashkin Andrei V AV Albert Daniel R DR Rajaseelan Edward E

IUCrData 20220708 Pt 7

The title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra-fluorido-borate counter-anion, crystallizes with one di-chloro-methane solvent mol-ecule per formula unit. The IrI atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cyclo-octa-1,5 ...[more]

PMID: 36341044

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