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Tetra-aqua-bis(1-hydr-oxy-2-naphthoato-?O)zinc(II).

ABSTRACT: In the title mononuclear complex, [Zn(C(11)H(7)O(3))(2)(H(2)O)(4)], the Zn(II) atom is located on a centre of inversion and is coordinated by two O atoms from two 1-hydr-oxy-2-naphthoate ligands and four water mol-ecules in an octa-hedral geometry. The structure is consolidated by inter-molecular O-H?O hydrogen bonding, as well as by a ?-? stacking inter-action [centroid-centroid distance 3.762?(2)Å] between adjacent naphthyl ring systems.

SUBMITTER: Song WD

PROVIDER: S-EPMC2914888 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Tetra-aqua-bis(1-hydr-oxy-2-naphthoato-κO)zinc(II).

Song Wen-Dong WD Yan Jian-Bin JB Wang Hao H Ji Li-Li LL

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title mononuclear complex, [Zn(C(11)H(7)O(3))(2)(H(2)O)(4)], the Zn(II) atom is located on a centre of inversion and is coordinated by two O atoms from two 1-hydr-oxy-2-naphthoate ligands and four water mol-ecules in an octa-hedral geometry. The structure is consolidated by inter-molecular O-H⋯O hydrogen bonding, as well as by a π-π stacking inter-action [centroid-centroid distance 3.762 (2)Å] between adjacent naphthyl ring systems. ...[more]

PMID: 21200621

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