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Tetra-aqua-bis[2-(2,4-dichloro-phen-oxy)acetato]nickel(II).

ABSTRACT: In the title complex, [Ni(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(4)], the Ni(II) atom (site symmetry ) adopts a slightly distorted NiO(6) octa-hedral coordination. An intra-molecular O-H⋯O hydrogen bond helps to establish the conformation. In the crystal, further O-H⋯O hydrogen bonds link the mol-ecules.

SUBMITTER: Chen W

PROVIDER: S-EPMC2969976 | biostudies-literature |

REPOSITORIES: biostudies-literature

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trans-Tetra-aqua-bis-[2-(4-chloro-phen-oxy)acetato-?O (1)]nickel(II).

Project description:In the title compound, [Ni(C8H6ClO3)2(H2O)4], the Ni(II) ion is located on a crystallographic inversion centre and is octa-hedrally coordinated by two 2-(4-chloro-phen-oxy)acetate ligands in axial positions and by four water mol-ecules in the equatorial plane. The acetate ligands are bound to the Ni(II) ion in a monodentate manner through a carboxyl-ate O atom. In the crystal, O-H?O hydrogen bonds link the mol-ecules, forming a two-dimensional supra-molecular network lying parallel to the ab plane.

| S-EPMC3588726 | biostudies-literature

Poly[[diaqua-bis[μ-(2,4-dichloro-phen-oxy)acetato]calcium(II)] monohydrate].

Project description:In the title coordination polymer, {[Ca(C(8)H(5)Cl(2)O(3))(2)(H(2)O)(2)]·H(2)O}(n), the Ca(II) atom is eight-coordinated by six O atoms from four different (2,4-dichloro-phen-oxy)acetate ligands and two water mol-ecules, and displays a distorted square-anti-prismatic coordination geometry. The compound forms an infinite zigzag chain through connection of the metal centers by (2,4-dichlorphen-oxy)acetate ligands and hydrogen bonding of coordinated and inter-stitial water mol-ecules. These chains are further hydrogen bonded with neighboring chains, forming a supra-molecular network.

| S-EPMC2961213 | biostudies-literature

Tetra-aqua-(1,10-phenanthroline-κN,N')magnesium(II) bis-[(2,4-dichloro-phen-yl)acetate].

Project description:In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexa-coordinated by two N atoms from a 1,10-phenanthroline ligand [Mg-N = 2.233 (2) Å] and four water mol-ecules [Mg-OW = 2.033 (2) and 2.043 (1) Å] in a distorted octa-hedral geometry. A twofold rotation axis passes through the Mg atom. In the crystal structure, the cations and anions are linked by inter-molecular O-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.804 (2) Å] into layers parallel to the ac plane.

| S-EPMC2961968 | biostudies-literature

Bis(2,4-dichloro-phen-oxy-acetato-?O,O)(5,5'-dimethyl-2,2'-bipyridine-?N,N')cobalt(II).

Project description:In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichloro-phen-oxy-acetate ligands and two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, displaying a distorted octa-hedral geometry. A three-dimensional supra-molecular structure is formed through inter-molecular C-H?O hydrogen bonds and ?-? stacking inter-actions between the pyridine and benzene rings [centroid-centroid distance = 3.779?(2)?Å].

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catena-Poly[zinc(II)-bis-[?-2-(2,4-dichloro-phen-oxy)acetato]].

Project description:The title polymeric compound, [Zn(C(8)H(5)Cl(2)O(3))(2)](n), was prepared by reaction of zinc(II) chloride with 2,4-dichloro-phenoxy-acetic acid and sodium hydroxide under hydro-thermal conditions. The Zn(II) atom is coordinated in a distorted tetra-hedral environment by four O atoms from four 2,4-dichloro-phenoxy-acetate ligands. Each ligand bridges two Zn(II) atoms, forming a polymeric chain along the a axis. Adjacent chains are connected via C-H?Cl hydrogen bonds.

| S-EPMC2979562 | biostudies-other

Tetra-aqua-bis-[2-(4-pyridyl-sulfan-yl)acetato-?N]nickel(II).

Project description:In the centrosymmetric title complex, [Ni(C(7)H(6)NO(2)S)(2)(H(2)O)(4)], the Ni(II) atom, located on a centre of inversion, is coordinated by two N atoms from two 2-(4-pyridyl-sulfan-yl)acetate ligands and four water O atoms in an octa-hedral geometry. In the crystal, inter-molecular O-H?O hydrogen bonds between the coordinated water mol-ecules and the carboxyl-ate group of the anionic 2-(4-pyridyl-sulfan-yl)acetate ligands link these discrete mononuclear units into a three-dimensional network.

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Poly[[bis-(?(2)-4,4'-bipyridine)[?(2)-(2,4-dichloro-phen-oxy)acetato]copper(I)] nitrate].

Project description:The title compound, {[Cu(2)(C(8)H(5)Cl(2)O(3))(C(10)H(8)N(2))(2)]NO(3)}(n) was prepared by reacting copper(II) nitrate with 4,4'-bipyridine (4,4'-bipy) and (2,4-dichloro-phen-oxy)acetic acid under solvothermal conditions. Each of two copper(I) atoms in the asymmetric unit is three-coordinated by two N atoms from two 4,4'-bipy ligands and one O atom from the (2,4-dichloro-phen-oxy)acetate ligand. As both ligands act as bridging ligands, a double-stranded chain structure is observed.

| S-EPMC2979712 | biostudies-literature

Tetra-aqua-bis-[2-(2-nitro-phen-yl)acetato-κO]cobalt(II).

Project description:The mol-ecule of the title compound, [Co(C8H6NO4)2(H2O)4], is centrosymmetric. It is a cobalt(II) complex, bearing two (2-nitro-phen-yl)acetate and four aqua ligands. The coordination around the Co(II) atom is distorted octa-hedral, defined by four O atoms of water mol-ecules in the equatorial plane and by two carboxyl-ate O atoms at axial positions. The dihedral angles between the benzene ring and the acetate and nitro groups are 61.90 (10) and 19.21 (11)°, respectively. The water mol-ecules form O-H⋯O hydrogen bonds with the nitro and carboxyl-ate groups, leading to a layered structural arrangement parallel to (001).

| S-EPMC4350698 | biostudies-literature

Tetra-pyridine-bis(trichloro-acetato)nickel(II).

Project description:The title compound, [Ni(C(2)Cl(3)O(2))(2)(C(5)H(5)N)(4)], was prepared by the reaction of pyridine and trichloro-acetatonickel(II) in ethanol solution at room temperature. The Ni(II) atom is located on a twofold rotation axis and has a slightly distorted octa-hedral coordination made up of four N atoms of the pyridine ligands and two O atoms of trichloro-acetate anions. The mol-ecular structure and packing are stabilized by intra- and inter-molecular C-H?O hydrogen-bonding inter-actions.

| S-EPMC2970073 | biostudies-literature

μ-Pyrazine-bis-[tetra-aqua-cadmium(II)] μ-pyrazine-bis-[tetra-acetato-cadmium(II)].

Project description:In the title dinuclear ionic complex, [Cd(2)(C(4)H(4)N(2))(H(2)O)(8)][Cd(2)(CH(3)CO(2))(8)(C(4)H(4)N(2))], the cation and anion are disordered equally over a site with symmetry mmm. The Cd(II) ions and the N atoms of the bridging pyrazine ligand lie on the inter-section of two crystallographic mirror planes. The C atoms of the bridging pyrazine ligand lie on one of these mirror planes, and the acetate groups and water mol-ecules lie across the inter-secting mirror planes. Each Cd(II) atom in the cation is five-coordinated by four O atoms from four water mol-ecules and one N atom from the bridging pyrazine ligand, whereas each Cd(II) in the anion is nine-coordinated by four pairs of O atoms from the bidentate acetate ligands and one N atom from the bridging pyrazine ligand. In the crystal structure, each anion is surrounded by eight nearest-neighbour cations and vice versa. The crystal structure is stabilized by ionic inter-actions as well as by C-H⋯O inter-actions.

| S-EPMC2961302 | biostudies-literature

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