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Diacetonitrile-[N,N'-bis-(3,4,5-trimethoxy-benzyl-idene)ethyl-enediamine]copper(I) perchlorate.

ABSTRACT: In the title compound, [Cu(C(2)H(3)N)(2)(C(22)H(28)N(2)O(6))]ClO(4), the Cu atom is coordinated by two N atoms from one bidentate Schiff base ligand and two N atoms from two acetonitrile groups. The Cu atom adopts a tetra-hedral geometry. The Cu-N(ligand) distances are 2.076?(3) and 2.089?(3)?Å, and the Cu-N(acetonitrile) distances are 1.964?(4) and 1.975?(4)?Å.

SUBMITTER: Khalaji AD

PROVIDER: S-EPMC2915121 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Diacetonitrile-[N,N'-bis-(3,4,5-trimethoxy-benzyl-idene)ethyl-enediamine]copper(I) perchlorate.

Khalaji Aliakbar Dehno AD Brad Korbanjhon K Zhang Yan Y

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

In the title compound, [Cu(C(2)H(3)N)(2)(C(22)H(28)N(2)O(6))]ClO(4), the Cu atom is coordinated by two N atoms from one bidentate Schiff base ligand and two N atoms from two acetonitrile groups. The Cu atom adopts a tetra-hedral geometry. The Cu-N(ligand) distances are 2.076 (3) and 2.089 (3) Å, and the Cu-N(acetonitrile) distances are 1.964 (4) and 1.975 (4) Å. ...[more]

PMID: 21200536

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