Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2-Chloro-N-[4-(dimethyl-amino)benzyl-idene]aniline.

ABSTRACT: In the title mol-ecule, C(15)H(15)ClN(2), the dihedral angle between the aromatic is 64.1?(2)°.

SUBMITTER: Li J

PROVIDER: S-EPMC2960011 | biostudies-other | 2008

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

2-Chloro-N-[4-(dimethyl-amino)benzyl-idene]aniline.

Li Jian J Liang Zu-Pei ZP Tai Xi-Shi XS

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

In the title mol-ecule, C(15)H(15)ClN(2), the dihedral angle between the aromatic is 64.1 (2)°. ...[more]

PMID: 21581295

Similar Datasets

N-[(E)-4-Chloro-benzyl-idene]-2,3-dimethyl-aniline.

Project description:In the title compound, C(15)H(14)ClN, the conformation about the C=N bond is trans and the dihedral angle between the aromatic rings is 51.48?(4)°. In the crystal, some very weak C-H?? inter-actions may help to establish the packing.

| S-EPMC3007017 | biostudies-literature

N-[(E)-4-Chloro-benzyl-idene]-2,4-dimethyl-aniline.

Project description:The title mol-ecule, C(15)H(14)ClN, exists in a trans configuration with respect to the C=N bond [1.2813?(16)?Å]. The dihedral angle between the benzene rings is 52.91?(6)°. The crystal structure is stabilized by weak inter-molecular C-H?? inter-actions.

| S-EPMC3212319 | biostudies-literature

4-Chloro-N-[4-(diethyl-amino)benzyl-idene]aniline.

Project description:The asymmetric unit of the title compound, C(17)H(19)ClN(2), contains two independent mol-ecules which differ by a 180° flip in the orientation of the 4-chloro-aniline unit with respect to the diethyl-amino-benzyl-idene unit [N=C-C-C = 10.0?(3) and -170.6?(2)°]. The dihedral angles between the two aromatic rings are 64.0?(1) and 66.5?(1)° in the two independent mol-ecules.

| S-EPMC2979698 | biostudies-literature

N-[4-(Dimethyl-amino)benzyl-idene]-4-ethoxy-aniline.

Project description:In the title compound, C(17)H(20)N(2)O, the mol-ecular core is planar, with a central C-N=C-C torsion angle of -179.3 (3)°. However, the overall geometry is not planar, with a dihedral angle of 61.96 (1)° between the two benzene rings, which adopt a trans configuration with respect to the C=N bond [1.269 (4) Å]. The bond lengths and angles are within normal ranges.

| S-EPMC2915009 | biostudies-literature

4-Chloro-N-(3,4,5-trimethoxy-benzyl-idene)aniline.

Project description:The title compound, C(16)H(16)ClNO(3), is a Schiff base displaying a trans configuration of the C=N double bond. In the crystal structure, inter-molecular C-H?N and bifurcated C-H?(O,O) hydrogen bonds are observed.

| S-EPMC2968176 | biostudies-literature

N-(4-Chloro-benzyl-idene)-4-methoxy-aniline.

Project description:The title compound, C(14)H(12)ClNO, was prepared by the reaction of 4-methoxy-aniline and 4-chloro-benzaldehyde in ethanol at 367?K. The mol-ecule is almost planar, with a dihedral angle between the two benzene rings of 9.1?(2)° and an r.m.s. deviation from the mean plane through all non-H atoms in the mol-ecule of 0.167?Å.

| S-EPMC2960562 | biostudies-literature

(Z)-N-(2-Chloro-benzyl-idene)aniline N-oxide.

Project description:In the title compound, C(13)H(10)ClNO, the central C-N bond has considerable double-bond character and the N-O bond indicates a formal negative charge on the O atom. The mol-ecule is stabilized by an intra-molecular C-H?O hydrogen bond. The geometry about the C=N bond is Z [C-C-N-O torsion angle = -4.2?(3)°] and the phenyl and benzene rings are trans-oriented around the C=N bond. The phenyl and benzene rings make a dihedral angle of 56.99?(2)°.

| S-EPMC3120351 | biostudies-literature

4-Chloro-N-[(E)-2,4-dichloro-benzyl-idene]aniline.

Project description:In the mol-ecule of the title compound, C(13)H(8)Cl(3)N, the 4-chloro-aniline and 2,4-dichloro-benzaldehyde moieties are planar with r.m.s. deviation of 0.0115 and 0.0116?Å, respectively, and are oriented at a dihedral angle of 13.94?(8)°.

| S-EPMC2983410 | biostudies-literature

(E)-4-Bromo-N-(2-chloro-benzyl-idene)-aniline.

Project description:In the title Schiff base mol-ecule, C(13)H(9)BrClN, the dihedral angle between the benzene rings is 49.8?(2)° and the mol-ecule has an E configuration about the C=N bond. In the crystal, there are no directional interactions but only van der Waals inter-molecular inter-action forces between neighbouring mol-ecules.

| S-EPMC3213634 | biostudies-literature

2,3-Dimethyl-N-[(E)-4-nitro-benzyl-idene]aniline.

Project description:In the title compound, C(15)H(14)N(2)O(2), the aromatic rings are oriented at a dihedral angle of 24.52?(5)°. The dihedral angle between the nitro group and its parent benzene ring is 9.22?(16)°. In the crystal, mol-ecules inter-act through aromatic ?-? stacking inter-actions [centroid-centroid separations = 3.8158?(14) and 3.9139?(14)?Å].

| S-EPMC3006706 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data