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Bis[4-(dimethyl-amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl-plumbate(IV).

ABSTRACT: The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra-gonally compressed octa-hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered halogen atom is an N-H?(Br/Cl) hydrogen-bond acceptor for the cation.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2967864 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis[4-(dimethyl-amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl-plumbate(IV).

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20081206 Pt 1

The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra-gonally compressed octa-hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered halogen atom is an N-H⋯(Br/Cl) hydrogen-bond acceptor for the cation. ...[more]

PMID: 21581489

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