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Di-?-oxido-bis-({2-[(R,R)-(-)-(2-amino-cyclo-hexyl)imino-meth-yl]-4-nitro-phenolato-?N,N',O}oxidovanadium(V)) dimethyl sulfoxide disolvate.

ABSTRACT: The title compound, [V(2)(C(13)H(16)N(3)O(3))(2)O(4)]·2C(2)H(6)OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide mol-ecules. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octa-hedral coordination geometry. Three atoms of the cyclo-hexane ring are each disordered over two sites, with occupancy factors of 0.501?(10) and 0.499?(10). C-H?O and N-H?O hydrogen bonds link the dimers and solvent mol-ecules into a supra-molecular network.

SUBMITTER: Romanowski G 

PROVIDER: S-EPMC2967873 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Di-μ-oxido-bis-({2-[(R,R)-(-)-(2-amino-cyclo-hexyl)imino-meth-yl]-4-nitro-phenolato-κN,N',O}oxidovanadium(V)) dimethyl sulfoxide disolvate.

Romanowski Grzegorz G   Wera Michał M   Sikorski Artur A  

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

The title compound, [V(2)(C(13)H(16)N(3)O(3))(2)O(4)]·2C(2)H(6)OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide mol-ecules. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octa-hedral coordination geometry. Three atoms of the cyclo-hexane ring are each disordered over two sites, with occupancy factors of 0.501 (10) and 0.499 (10). C-H⋯O and N-H  ...[more]

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