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Bis[4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene-?O)benzohydrazidato-?O,N']cadmium(II) dimethyl sulfoxide disolvate.

ABSTRACT: The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octa-hedral geometry. Each anion occupies meridional sites of the octa-hedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide mol-ecule is a hydrogen-bond acceptor to the -NH- unit, and O-H?O hydrogen bonds link mol-ecules into a supra-molecular chain.

SUBMITTER: Mohd Lair N

PROVIDER: S-EPMC2977592 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Bis[4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene-κO)benzohydrazidato-κO,N']cadmium(II) dimethyl sulfoxide disolvate.

Mohd Lair Nooraziah N Mohd Ali Hapipah H Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090422 Pt 5

The metal atom in the title compound, [Cd(C(15)H(13)N(2)O(4))(2)]·2C(2)H(6)OS, is twice O,N,O'-chelated by two symmetry-related Schiff base ligands to define a trans-N(2)O(4) octa-hedral geometry. Each anion occupies meridional sites of the octa-hedron; the metal atom lies on a special position of site symmetry 2. The dimethyl sulfoxide mol-ecule is a hydrogen-bond acceptor to the -NH- unit, and O-H⋯O hydrogen bonds link mol-ecules into a supra-molecular chain. ...[more]

PMID: 21583778

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