Browse
Submit Data
Databases
API
Help

Dataset Information

23 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(?-4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolato)bis-[chlorido(dimethyl sulfoxide)-iron(III)] dimethyl sulfoxide disolvate.

ABSTRACT: In the centrosymmetric dimeric title complex, [Fe(2)(C(14)H(10)N(2)O(4))(2)Cl(2)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, two {Fe(L)Cl(DMSO)} units (L is the tridentate ligand 4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolate; DMSO is dimethyl sulfoxide) are bridged by two O atoms, with an Fe?Fe separation of 3.1838?(8)?Å. The coordination polyhedron of the Fe(III) atoms can be described as distorted octa-hedral, with four Fe-O, one Fe-N and one Fe-Cl coordination bonds. The L ligand is not planar, the dihedral angle between the 2-(oxidometh-yl)phen-yl]imino and 4-nitro-2-(imino-meth-yl)phenolate planes being 48.54?(9)°. The solvent DMSO molecule is disordered over two orientations with equal occupancy.

SUBMITTER: Chygorin EN

PROVIDER: S-EPMC3344389 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(μ-4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolato)bis-[chlorido(dimethyl sulfoxide)-iron(III)] dimethyl sulfoxide disolvate.

Chygorin Eduard N EN Rusanova Julia A JA Zubatyuk Roman I RI Shishkin Oleg V OV

Acta crystallographica. Section E, Structure reports online 20120425 Pt 5

In the centrosymmetric dimeric title complex, [Fe(2)(C(14)H(10)N(2)O(4))(2)Cl(2)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, two {Fe(L)Cl(DMSO)} units (L is the tridentate ligand 4-nitro-2-{[2-(oxidometh-yl)phen-yl]imino-meth-yl}phenolate; DMSO is dimethyl sulfoxide) are bridged by two O atoms, with an Fe⋯Fe separation of 3.1838 (8) Å. The coordination polyhedron of the Fe(III) atoms can be described as distorted octa-hedral, with four Fe-O, one Fe-N and one Fe-Cl coordination bonds. The L ligand is not planar ...[more]

PMID: 22590151

Similar Datasets

Di-?-oxido-bis-({2-[(R,R)-(-)-(2-amino-cyclo-hexyl)imino-meth-yl]-4-nitro-phenolato-?N,N',O}oxidovanadium(V)) dimethyl sulfoxide disolvate.

Project description:The title compound, [V(2)(C(13)H(16)N(3)O(3))(2)O(4)]·2C(2)H(6)OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide mol-ecules. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octa-hedral coordination geometry. Three atoms of the cyclo-hexane ring are each disordered over two sites, with occupancy factors of 0.501?(10) and 0.499?(10). C-H?O and N-H?O hydrogen bonds link the dimers and solvent mol-ecules into a supra-molecular network.

| S-EPMC2967873 | biostudies-other

Bis{2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolato-?N,O}nickel(II) N,N-dimethyl-formamide disolvate.

Project description:The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolate ligand in a square-planar coordination environment. The mol-ecule is linked to a solvent mol-ecule by an indole-dimethyl-formamide N-H?O hydrogen bond.

| S-EPMC2961391 | biostudies-literature

Bis{2-[(2-hy-droxy-2-methyl-prop-yl)imino-meth-yl]-4-nitro-phenolato}nickel(II) dimethyl-formamide monosolvate.

Project description:In the title compound, [Ni(C(11)H(13)N(2)O(4))(2)]·C(3)H(7)NO, the Ni(II) ion is octa-hedrally coordinated in an N(2)O(4) environment by two identical Schiff base ligands. The Ni-O bond lengths range from 2.004?(2) to 2.106?(2)?Å, while the Ni-N bond lengths are 2.038?(2) and 2.0465?(19)?Å. The cis bond angles range from 78.64?(8) to 97.30?(8)°, with the former being due to the small bite of the amino-alcohol ligand, while the trans bond angles range from 167.86?(8) to 171.23?(8)°. One of the alcohol H atoms forms a hydrogen bond with the dimethyl-formamide (DMF) solvent mol-ecule, while the other links mol-ecules into chains along the b axis through inter-molecular O-H?O hydrogen bonds. There are bifurcated C-H?O inter-actions involving one of the nitro groups between parallel stacks of mol-ecules in the b-axis direction.

| S-EPMC3200578 | biostudies-literature

Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).

Project description:The title compound, [Cu2(C9H10NO2)4], is built of discrete centrosymmetric dimers. The Cu(II) atoms are each five coordinated by two deprotonated Schiff base ligands that are bonded differently to the metal atoms. Of the two phenolate O atoms, one is coordinated to one Cu(II) atom, whereas another bridges the two metal atoms. The basal plane of the square pyramid around Cu(II) atoms is formed by the imino N and phenolate O atoms of the bidentate and the monodentate/bidentate Schiff base ligands. The bridging phenolate oxygen occupies the apical position of the coordination sphere with a considerably longer Cu-O bond length. In the crystal, the dimeric mol-ecules pack relative to each other in such a way that the Cu2O2 planes of adjacent dimers are orthogonal.

| S-EPMC3790358 | biostudies-literature

Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

Project description:The title compound, [CoCd(C9H10NO2)3Cl2]·H2O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171-184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol-ecules with no crystallographically imposed symmetry and water mol-ecules of crystallization. The overall geometry about the cobalt(III) ion is octa-hedral with an N3O3 environment; each ligand acts as a meridional ONO donor. The CdII coordination sphere approximates an irregular square pyramid with a chlorine atom at the apex. There is significant shortening of a Cd-O bond length to the oxygen atom of the methoxo group on one of the ligands [2.459 (3) Å] compared to the corresponding distance in the published structure [2.724 (7) Å], while other Cd-Cl/N/O bonds remain roughly the same. In the crystal lattice, the heterometallic mol-ecules, which are related by the crystallographic n-glide plane and inter-linked by weak hydrogen bonds to solvent water mol-ecules, form columns along [101]. Adjacent columns lie anti-parallel to each other.

| S-EPMC6218914 | biostudies-literature

Bis[2-(cyclo-pentyl-imino-meth-yl)-4-nitro-phenolato-?N,O]cobalt(II).

Project description:In the title compound, [Co(C(12)H(13)N(2)O(3))(2)], the Co(II) ion is situated on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related Schiff base 2-(cyclo-pentyl-imino-meth-yl)-4-nitro-phenolate ligands (L) in a distorted tetra-hedral geometry. The cyclo-pentyl ring in L is disordered over two conformations in a 0.640?(19):0.360?(19) ratio.

| S-EPMC3051424 | biostudies-literature

Chlorido{?-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-?-oxido-dicopper(II) trihydrate.

Project description:In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H?Cl hydrogen bonds while O-H?O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

| S-EPMC3379123 | biostudies-literature

Bis{2,4-dichloro-6-[3-(dimethyl-amino)propyl-imino-meth-yl]phenolato}copper(II).

Project description:In the title complex, [Cu(C(12)H(15)Cl(2)N(2)O)(2)], the Cu(II) ion is coordinated by one N,O-bidentate and one N,N',O-tridentate Schiff base ligand, resulting in a distorted CuN(3)O(2) square-based pyramidal coordination for the metal ion, with the O atoms lying trans to each other in the basal plane.

| S-EPMC2970479 | biostudies-literature

3,3'-Bis(4-nitro-phen-yl)-1,1'-(p-phenyl-ene)dithio-urea dimethyl sulfoxide disolvate.

Project description:The asymmetric unit of the title compound, C(22)H(16)N(6)O(6)S(2)·2C(2)H(6)OS, consists of one half-mol-ecule of the centrosymmetric thiourea derivative and one molecule of dimethyl sulfoxide (DMSO). The carbonyl group forms an intra-molecular hydrogen bond with the NH group, creating a six-membered (C-N-C-N-H?O) ring. Two other N-H?O hydro-gen bonds link one mol-ecule of the thio-urea to two mol-ecules of DMSO.

| S-EPMC2961527 | biostudies-literature

Bis[2-({[2-(methyl-sulfan-yl)phen-yl]imino}-meth-yl)phenolato-?(2) N,O]zinc chloro-form disolvate.

Project description:The monomeric title complex, [Zn(C14H12NOS)2]·2CHCl3 or L2Zn·2CHCl3, where L is the 2-({[2-(methyl-sulfan-yl)phen-yl]imino}-meth-yl)phenolate anion, may be obtained by the reaction of LZnEt with benzyl alcohol or by the reaction of two equivalents of LH with ZnEt2 in tetra-hydro-furan. The Zn atom, located on a twofold axis, is four-coordinated in a distorted tetra-hedral geometry by two O atoms [Zn-O = 1.9472?(19)?Å] from the phenolate anions and two imine N atoms [Zn-N = 2.054?(2)?Å].

| S-EPMC3588749 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data