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N-(2-Pyridylmethyleneamino)dehydro-abietylamine.

ABSTRACT: The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,2,3,4,4a,9,10,10a-octa-hydro-phenanthren-1-yl]-N-[(E)-2-pyridylmethyleneamino]methanamine}, C(26)H(33)N(2), has been synthesized from dehydro-abietylamine. The two cyclo-hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, whereas the benzene and pyridine rings are almost planar, and the dihedral angle between them is 80.4°. The two methyl groups directly attached to the tricyclic nucleus are on the same side of the tricyclic hydro-phenanthrene structure.

SUBMITTER: Wu Y

PROVIDER: S-EPMC2968828 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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N-(2-Pyridylmethyleneamino)dehydro-abietylamine.

Wu Yong Y Rao Xiao-Ping XP Wang Zong-De ZD Song Zhan-Qian ZQ Yao Xu-Jie XJ

Acta crystallographica. Section E, Structure reports online 20090319 Pt 4

The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,2,3,4,4a,9,10,10a-octa-hydro-phenanthren-1-yl]-N-[(E)-2-pyridylmethyleneamino]methanamine}, C(26)H(33)N(2), has been synthesized from dehydro-abietylamine. The two cyclo-hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, whereas the benzene and pyridine rings are almost planar, and the dihedral angle between them is 80.4°. The two methyl groups directly attached to the tricycli ...[more]

PMID: 21582511

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