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Poly[tetra-kis(2,2'-bipyridine)undeca-?-oxido-hexa-oxidodicopper(II)hexa-vanadium(V)].

ABSTRACT: In the title organic-inorganic hybrid vanadate complex, [Cu(2)V(6)O(17)(C(10)H(8)N(2))(4)](n), the Cu(II) atom is six-coordinated by two chelating 2,2'-bipyridine (bipy) ligands and two vanadate O atoms in a distorted octa-hedral geometry. Two [Cu(bipy)(2)V(3)O(8)] units are linked by a bridging O atom, which lies on an inversion center, forming a dimeric unit. The dimeric units are further connected by bridging vanadate O atoms into a two-dimensional layer parallel to (100). The layers are connected by weak C-H?O hydrogen bonds.

SUBMITTER: Cui JW

PROVIDER: S-EPMC2979115 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Poly[tetra-kis(2,2'-bipyridine)undeca-μ-oxido-hexa-oxidodicopper(II)hexa-vanadium(V)].

Cui Ji-Wen JW Cui Xiao-Bing XB Yu Hai-Hui HH Xu Ji-Qing JQ Wang Shu-Hong SH

Acta crystallographica. Section E, Structure reports online 20100424 Pt 5

In the title organic-inorganic hybrid vanadate complex, [Cu(2)V(6)O(17)(C(10)H(8)N(2))(4)](n), the Cu(II) atom is six-coordinated by two chelating 2,2'-bipyridine (bipy) ligands and two vanadate O atoms in a distorted octa-hedral geometry. Two [Cu(bipy)(2)V(3)O(8)] units are linked by a bridging O atom, which lies on an inversion center, forming a dimeric unit. The dimeric units are further connected by bridging vanadate O atoms into a two-dimensional layer parallel to (100). The layers are conn ...[more]

PMID: 21579049

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