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Bis(cyanido-?C)bis-(cyclo-hexyl-amine-?N)mercury(II).

ABSTRACT: In the title compound, [Hg(CN)(2)(C(6)H(13)N)(2)], the Hg(II) ion adopts an extremely distorted HgC(2)N(2) tetra-hedral coordination. The crystal packing is influenced by weak N-H?N hydrogen bonds between the amino groups and the cyanide N atoms, resulting in chains of mol-ecules propagating in [110]. Both cyclo-hexyl-amine mol-ecules adopt chair conformations.

SUBMITTER: Ejaz

PROVIDER: S-EPMC2979811 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Bis(cyanido-κC)bis-(cyclo-hexyl-amine-κN)mercury(II).

Ejaz Khan Islam Ullah IU Harrison William T A WT

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

In the title compound, [Hg(CN)(2)(C(6)H(13)N)(2)], the Hg(II) ion adopts an extremely distorted HgC(2)N(2) tetra-hedral coordination. The crystal packing is influenced by weak N-H⋯N hydrogen bonds between the amino groups and the cyanide N atoms, resulting in chains of mol-ecules propagating in [110]. Both cyclo-hexyl-amine mol-ecules adopt chair conformations. ...[more]

PMID: 21579691

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