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Triphen-yl[(4-phenyl-benzo-yl)meth-yl]phospho-nium trifluoro-methane-sulfonate.

ABSTRACT: In the cation of the title compound, C(32)H(26)OP(+)·CF(3)O(3)S(-), the dihedral angle between the benzene rings of the biphenyl group is 42.37?(8)°. In the crystal, the cations and anions inter-act through inter-molecular C-H?O hydrogen bonds, forming chains parallel to the b axis. These chains are further linked by C-H?? stacking inter-actions into layers parallel to the bc plane.

SUBMITTER: Rizzoli C

PROVIDER: S-EPMC2983122 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Triphen-yl[(4-phenyl-benzo-yl)meth-yl]phospho-nium trifluoro-methane-sulfonate.

Rizzoli Corrado C Karami Kazem K Salah Mina Mohamadi MM

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

In the cation of the title compound, C(32)H(26)OP(+)·CF(3)O(3)S(-), the dihedral angle between the benzene rings of the biphenyl group is 42.37 (8)°. In the crystal, the cations and anions inter-act through inter-molecular C-H⋯O hydrogen bonds, forming chains parallel to the b axis. These chains are further linked by C-H⋯π stacking inter-actions into layers parallel to the bc plane. ...[more]

PMID: 21587644

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