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[(Methyl-carbamothio-yl)disulfan-yl]methyl N-methyl-carbamodithio-ate.

ABSTRACT: The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl-carbamodithioic acid using methyl-amine and carbon disulfide. In the mol-ecule, two dithio-carbamate groups are bridged by a -CH(2)S- unit. The C-S-S-C torsion angle is -90.13?(11)°. The crystal structure is stabilized by N-H?S inter-actions between neighbouring mol-ecules. An intra-molecular N-H?S hydrogen bond also occurs.

SUBMITTER: Khan H

PROVIDER: S-EPMC2983331 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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[(Methyl-carbamothio-yl)disulfan-yl]methyl N-methyl-carbamodithio-ate.

Khan Hizbullah H Aziz Muhammad M Neuhausen Christine C Murtaza Ghulam G Shaheen Farkhanda F

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

The title compound, C(5)H(10)N(2)S(5), was unintentionally obtained as the product of an attempted synthesis of a methyl-carbamodithioic acid using methyl-amine and carbon disulfide. In the mol-ecule, two dithio-carbamate groups are bridged by a -CH(2)S- unit. The C-S-S-C torsion angle is -90.13 (11)°. The crystal structure is stabilized by N-H⋯S inter-actions between neighbouring mol-ecules. An intra-molecular N-H⋯S hydrogen bond also occurs. ...[more]

PMID: 21587641

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