Browse
Submit Data
Databases
API
Help

Dataset Information

7 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[(dimethyl-formamide-?O)cobalt(II)]-bis-[?-(4-nitro-phenyl)-cyanamido]-?N:N;?N:N].

ABSTRACT: In the title coordination polymer, [Co(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)](n), the Co(II) atom is five-coordinated in a distorted square-pyramidal CoON(4) geometry with the O atom from a dimethyl-formamide mol-ecule in an equatorial position. The bridging phenyl-cyanamide anions generate an infinite chain propagating in [001].

SUBMITTER: Chiniforoshan H

PROVIDER: S-EPMC2983514 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

catena-Poly[[(dimethyl-formamide-κO)cobalt(II)]-bis-[μ-(4-nitro-phenyl)-cyanamido]-κN:N;κN:N].

Chiniforoshan Hossein H Shirinfar Bahare B Jalilpour Soghra S Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20100224 Pt 3

In the title coordination polymer, [Co(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)](n), the Co(II) atom is five-coordinated in a distorted square-pyramidal CoON(4) geometry with the O atom from a dimethyl-formamide mol-ecule in an equatorial position. The bridging phenyl-cyanamide anions generate an infinite chain propagating in [001]. ...[more]

PMID: 21580266

Similar Datasets

catena-Poly[[(dimethyl-formamide-?O)copper(II)]-bis-(?-4-nitro-phenyl-cyanamido-?N:N)].

Project description:In the title compound, [Cu(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated in a distorted square-pyramidal geometry, with the N atoms in equatorial positions and the dimethyl-formamide O atom in an axial position. The dihedral angle between adjacent benzene rings is 70.33?(12)°.

| S-EPMC2969028 | biostudies-literature

catena-Poly[[bis-(dimethyl-formamide-?O)cadmium]-bis-(?-4-nitro-phenyl-cyanamido-?N:N)].

Project description:In the title coordination polymer, [Cd(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)(2)](n), the Cd(II) atom, lying on an inversion center, is six-coordinated in a distorted N(4)O(2) octa-hedral geometry. The N atoms of the 4-nitrophenylcyanamide anions form the equatorial plane and the O atoms of the dimethyl-formamide mol-ecules occupy the axial positions. The anions act as bridging ligands, connecting the Cd atoms into a one-dimensional coordination polymer along [100].

| S-EPMC3297207 | biostudies-literature

catena-Poly[[bis-(dimethyl-ammonium) [cadmate(II)-bis-(?-1,1':4',1''-terphenyl-3,3''-dicarboxyl-ato)]] dimethyl-formamide disolvate].

Project description:In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two ?(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two ?(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10].

| S-EPMC3050304 | biostudies-literature

catena-Poly[[bis-(N,N'-dimethyl-formamide)cadmium(II)]-?(2)-oxalato].

Project description:The title compound, [Cd(C(2)O(4))(C(3)H(7)NO)(2)](n), is isostructural with its Mn(II) analogue. The structure comprises zigzag polymeric chains with the oxalate groups situated on inversion centres and the Cd(II) atoms located on twofold rotation axes. The coordination geometry around Cd(II) is distorted octa-hedral and the intra-chain Cd?Cd distance is 5.842?(1)?Å. C-H?O hydrogen bonds exist between the parallel polymeric chains.

| S-EPMC2915118 | biostudies-other

Hexakis(N,N-dimethyl-formamide-?O)cobalt(II) bis-(perchlorate).

Project description:The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H?O hydrogen-bonding inter-actions.

| S-EPMC2983736 | biostudies-literature

catena-Poly[[[aqua-chlorido-manganese(II)]-bis-[?-1,1'-(oxydi-p-phenyl-ene)di-1H-imidazole-?N:N]] chloride dimethyl-formamide mono-solvate monohydrate].

Project description:The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethyl-formamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1'-(oxydi-p-phenyl-ene)di-1H-imidazole] metallocyclic rings that exhibit inversion symmetry. The coordination about the Mn(II) ions is distorted octahedral with a MnClN(4)O coordination set. In the crystal, the polymeric chains are linked by O-H?Cl hydrogen bonds, forming a two-dimensional network parallel to (100). A number of C-H?Cl and C-H?O inter-actions are also present.

| S-EPMC3051568 | biostudies-literature

catena-Poly[[aqua-(2,2'-bipyridyl)cobalt(II)]-μ-5-nitro-isophthalato].

Project description:In the crystal structure of the title compound, [Co(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers, which are approximately related by noncrystallographic inversion symmetry. Each zigzag chain is constructed from one Co(II) ion, one O-monodentate 5-nitro-isophthalate (ndc) dianion, one N,N'-bidentate 2,2'-bipyridyl ligand and one water mol-ecule. A symmetry-generated O,O'-bidentate ndc dianion completes the cobalt coordination environment, which could be described as very distorted cis-CoN(2)O(4) octa-hedral. The bridging ndc ligands result in parallel chains running along the a direction, and O-H⋯O hydrogen bonds arising from the water mol-ecules complete the structure.

| S-EPMC2960127 | biostudies-literature

catena-Poly[[bis-(dimethyl-formamide-?O)cadmium(II)]-di-?(2)-dicyanamido-?N:N].

Project description:In the title compound, [Cd(C(2)N(3))(2)(C(3)H(7)NO)(2)], the Cd(2+) ion lies on an inversion center and adopts an octa-hedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethyl-formamide O atoms occupy the axial positions. The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010].

| S-EPMC2972080 | biostudies-other

Poly[bis-(?(2)-4,4'-bipyridine)bis-(3-nitro-benzoato)cobalt(II)].

Project description:The hydro-thermal reaction of cobalt nitrate with 4,4'-bipyridine and 3-nitro-benzoic acid lead to the formation of the title complex, [Co(C(7)H(4)NO(4))(2)(C(10)H(8)N(2))(2)](n). In the crystal structure, the Co(II) atoms are coordinated by two terminal carboxyl-ate anions and four 4,4'-bipyridine ligands within slightly distorted octa-hedra. The Co(II) atom and one of the two independent 4,4'-bipyridine ligands are located on a twofold rotation axis, while the second independent 4,4'-bipyridine mol-ecule is located on a centre of inversion. One of the two rings of one 4,4'-bipyridine ligand is disordered over two orientations and was refined using a split model [occupancy ratio 0.68?(2):0.32?(2)]. The Co(II) atoms are connected by the 4,4'-bipyridine ligands into layers, which are located parallel to the ab plane.

| S-EPMC2971117 | biostudies-literature

catena-Poly[[[bis-(N,N-dimethyl-formamide)iron(II)]-{μ-2,2'-bis-(diphenyl-phosphino-yl)-N,N'-[(1R,2R)-cyclo-hexane-1,2-di-yl]dibenzamide}] bis-(perchlorate) N,N-dimethyl-formamide disolvate].

Project description:The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un-ex-pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino-cyclo-hexane-N,N'-bis-(2'-di-phenyl-phosphinobenzo-yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl-formamide (DMF) under reflux conditions. The polymeric complex is characterized by Fe(II) metal centers that are coordinated by two oxidized Trost ligands, each coordinated in a bidentate fashion in a square plane, along with two DMF mol-ecules above and below the plane [average Fe-O(DMF) = 2.086 (4) Å], forming an overall pseudo-octa-hedral geometry. The Trost ligand binds adjacent Fe(II) centers, each Fe(II) being bound through the O atom of one of the phosphine oxides [average Fe-O(PPh2) = 2.115 (4) Å] and the carbonyl O atom of the adjacent amide [average Fe-O(amide) = 2.192 (3) Å]. Disorder is observed in the co-solvated solvent: there are two DMF mol-ecules per Fe(II) centre, which were modeled as one DMF mol-ecule with complete occupancy and the other being modeled in two positions with equal occupancy. Disorder was also observed with one of the perchlorate anions, which was modeled in two positions with 0.75:0.25 occupancy.

| S-EPMC2971940 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data