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9-(2-Ethyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

ABSTRACT: In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through ?-? inter-actions between the acridine ring systems. These dimers are further linked by C-H?? inter-actions. The cations and anions are connected by C-H?O and C-F?? inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 20.8?(1)°. The carboxyl group is twisted at an angle of 66.2?(1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel in the lattice.

SUBMITTER: Trzybinski D

PROVIDER: S-EPMC2984008 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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9-(2-Ethyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Trzybiński Damian D Krzymiński Karol K Sikorski Artur A Malecha Piotr P Błażejowski Jerzy J

Acta crystallographica. Section E, Structure reports online 20100313 Pt 4

In the crystal structure of the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems. These dimers are further linked by C-H⋯π inter-actions. The cations and anions are connected by C-H⋯O and C-F⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 20.8 (1)°. The carboxyl group is twisted at an angle of 66.2 (1)° relative to the acridine skeleton. The mean planes of ...[more]

PMID: 21580656

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