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Bis(isopropyl-triphenyl-phospho-nium) di-?-iodido-bis-[iodidocopper(I)].

ABSTRACT: The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl-phospho-nium iodide in hydroxy-acetone (acetol), shows an already known Cu(2)I(4) (2-) anion with a planar conformation [Cu-I range = 2.5108?(3)-2.5844?(3)?Å and I-Cu-I range = 110.821?(10)-125.401?(10)°].

SUBMITTER: Jalilian E

PROVIDER: S-EPMC2984081 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Bis(isopropyl-triphenyl-phospho-nium) di-μ-iodido-bis-[iodidocopper(I)].

Jalilian Ehsan E Lidin Sven S

Acta crystallographica. Section E, Structure reports online 20100324 Pt 4

The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl-phospho-nium iodide in hydroxy-acetone (acetol), shows an already known Cu(2)I(4) (2-) anion with a planar conformation [Cu-I range = 2.5108 (3)-2.5844 (3) Å and I-Cu-I range = 110.821 (10)-125.401 (10)°]. ...[more]

PMID: 21580528

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