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Bis(4,6-dimethyl-pyrimidine-2-thiol-ato)dimethyl-tin(IV).

ABSTRACT: The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol-ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl-pyrimidine-2-thiol-ate anions in a distorted SnS(2)C(2) tetra-hedral geometry. In the two mol-ecules, the S-Sn-S bond angles are 87.70?(5) and 88.93?(4)°, while the C-Sn-C bond angles are 125.7?(3) and 125.9?(2)°. Weak C-H?N hydrogen bonding is present in the crystal structure.

SUBMITTER: Shi Y

PROVIDER: S-EPMC3007831 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Bis(4,6-dimethyl-pyrimidine-2-thiol-ato)dimethyl-tin(IV).

Shi Yang Y Zhang Ru-Fen RF Ma Chun-Lin CL

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol-ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl-pyrimidine-2-thiol-ate anions in a distorted SnS(2)C(2) tetra-hedral geometry. In the two mol-ecules, the S-Sn-S bond angles are 87.70 (5) and 88.93 (4)°, while the C-Sn-C bond angles are 125.7 (3) and 125.9 (2)°. Weak C-H⋯N hydrogen bonding is present in the crystal structure. ...[more]

PMID: 21588562

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