Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2-Methyl-N'-(4-nitro-benzyl-idene)benzohydrazide.

ABSTRACT: The title hydrazone compound, C(15)H(13)N(3)O(3), was prepared by the condensation of 4-nitro-benzaldehyde with 2-methyl-benzohydrazide in methanol. The dihedral angle between the two benzene rings is 14.8?(2)°. In the crystal, mol-ecules are linked through inter-molecular N-H?O hydrogen bonds, forming chains along the a axis.

SUBMITTER: Tang CB

PROVIDER: S-EPMC3009122 | biostudies-other | 2010

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

2-Methyl-N'-(4-nitro-benzyl-idene)benzohydrazide.

Tang Chun-Bao CB

Acta crystallographica. Section E, Structure reports online 20101002 Pt 11

The title hydrazone compound, C(15)H(13)N(3)O(3), was prepared by the condensation of 4-nitro-benzaldehyde with 2-methyl-benzohydrazide in methanol. The dihedral angle between the two benzene rings is 14.8 (2)°. In the crystal, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains along the a axis. ...[more]

PMID: 21588928

Similar Datasets

(E)-4-Methyl-N'-(3-nitro-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(3), the dihedral angle between the benzene rings is 1.01?(3)° and that between the nitro group and its attached ring is 5.99?(15)°. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds generating C(4) chains along [010].

| S-EPMC3379220 | biostudies-literature

N'-[(Z)-4-Methyl-benzyl-idene]-4-nitro-benzohydrazide monohydrate.

Project description:In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03 (2)°. In the crystal structure, adjacent hydrazide mol-ecules are linked into dimers by water mol-ecules; these dimers are then stacked along the b axis. Inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds and a π-π stacking inter-action between the nitro-benzene and tolyl rings with a centroid-centroid distance of 3.8208 (3) Å are observed. There is also a short O⋯N contact [2.6824 (7) Å].

| S-EPMC2960119 | biostudies-literature

(E)-3-Methyl-N'-(4-nitro-benzyl-idene)benzohydrazide methanol monosolvate.

Project description:The title hydrazone compound, C(15)H(13)N(3)O(3)·CH(3)OH, crystallized as a methanol solvate. The hydrazone mol-ecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3?(3)°. In the crystal, the hydrazone mol-ecules are linked via the methanol solvent mol-ecule through N-H?O and O-H?O hydrogen bonds, so forming chains propagating along the a-axis direction.

| S-EPMC3297325 | biostudies-literature

(E)-4-Nitro-N'-(3-nitro-benzyl-idene)benzohydrazide.

Project description:The title compound, C(14)H(10)N(4)O(5), has an E conformation with respect to the C=N bond. The dihedral angle between the benzene rings is 2.41?(14)°. In the crystal, mol-ecules are linked through N-H?O hydrogen bonds to form chains along the c axis. C-H?O inter-actions are also present, linking the chains to form a three-dimensional network.

| S-EPMC3295447 | biostudies-literature

N'-(2-Chloro-benzyl-idene)-4-nitro-benzohydrazide.

Project description:In the title compound, C(14)H(10)ClN(3)O(3), the dihedral angle between the benzene rings is 6.64?(13)°. In the crystal, mol-ecules are linked through N-H?O hydrogen bonds, forming chains running along the c axis direction.

| S-EPMC3275020 | biostudies-literature

2-Hy-droxy-N'-(5-hy-droxy-2-nitro-benzyl-idene)-3-methyl-benzohydrazide.

Project description:The title compound, C(15)H(13)N(3)O(5), was prepared by condensing 5-hy-droxy-2-nitro-benzaldehyde and 2-hy-droxy-3-methyl-benzohydrazide in methanol. The two benzene rings make a dihedral angle of 3.9?(3)°. An intra-molecular O-H?O hydrogen bond is observed. The crystal structure is stabilized by inter-molecular O-H?O and N-H?O hydrogen bonds, and C-H?O and ?-? inter-actions [centroid-centroid distances = 3.5658?(17)-3.9287?(19)?Å].

| S-EPMC3297290 | biostudies-literature

N'-(3-Hy-droxy-benzyl-idene)-4-nitro-benzohydrazide.

Project description:The title mol-ecule, C(14)H(11)N(3)O(4), is approximately planar, with an inter-planar angle between the two benzene rings of 5.8?(2)°. In the crystal, four mol-ecules are linked by an R(4) (4)(12) motif with pairs of strong O-H?O and N-H?O hydrogen bonds. The motif is situated about the crystallographic centres of symmetry and it is composed of two pairs of parallel mol-ecules. This quadruplet of mol-ecules is further extended by symmetry-equivalent hydrogen bonds to form layers parallel to the (10) plane. In addition to the hydrogen bonds, there is also a weak ?-? inter-action between the benzene rings.

| S-EPMC3009013 | biostudies-literature

(E)-N'-(3,4-Dihydroxy-benzyl-idene)-4-nitro-benzohydrazide.

Project description:In the title Schiff base compound, C(14)H(11)N(3)O(5), the dihedral angle between the two benzene rings is 1.6?(1)°. The mol-ecule displays an E configuration about the C=N bond. An intra-molecular O-H?O hydrogen bond is observed. In the crystal, mol-ecules are linked into layers parallel to (101) by O-H?O, N-H?O and C-H?O hydrogen bonds. One of the hydroxyl groups is disordered over two positions, with occupancies of 0.643?(5) and 0.357?(5).

| S-EPMC2977219 | biostudies-literature

N'-(4-Hy-droxy-benzyl-idene)-4-nitro-benzohydrazide.

Project description:The title compound, C(14)H(11)N(3)O(4), was prepared by the reaction of 4-nitro-benzohydrazide with 4-hy-droxy-benz-alde-hyde. The whole mol-ecule of the compound is approximately planar, with a mean deviation from the least-squares plane through all the non-H atoms of 0.050?(2)?Å; the dihedral angle between the two benzene rings is 2.0?(2)°. In the crystal, the benzohydrazide mol-ecules are linked through inter-molecular O-H?O and N-H?O hydrogen bonds, forming layers in the bc plane.

| S-EPMC3009258 | biostudies-literature

4-Meth-oxy-N'-(3-nitro-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(4), the dihedral angle between the benzene rings is 3.1?(3)°. The mol-ecule displays an E conformation about the C=N bond. In the crystal, mol-ecules are linked via N-H?O hydrogen bonds, generating chains that propagate along the b-axis direction. There is also a C-H?O inter-action present.

| S-EPMC3379315 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data