Browse
Submit Data
Databases
API
Help

Dataset Information

9 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dinitro-sylbis[tris-(4-chloro-phen-yl)phosphane]iron.

ABSTRACT: The title dinitrosyl iron diphosphane complex, [Fe(NO)(2)(C(18)H(12)Cl(3)P)(2)] or Fe(NO)(2)L(2) [L = P(C(6)H(4)-p-Cl)(3)] belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as dinitrosyl iron compounds (DNICs). The iron atom is tetra-hedrally coordinated by two phosphane ligands and two NO groups with Fe-N-O bond angles of 178.76?(15) and 177.67?(14)°.

SUBMITTER: Jones MW

PROVIDER: S-EPMC3051485 | biostudies-other | 2011 Jan

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Dinitro-sylbis[tris-(4-chloro-phen-yl)phosphane]iron.

Jones Myron W MW Powell Douglas R DR Richter-Addo George B GB

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

The title dinitrosyl iron diphosphane complex, [Fe(NO)(2)(C(18)H(12)Cl(3)P)(2)] or Fe(NO)(2)L(2) [L = P(C(6)H(4)-p-Cl)(3)] belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as dinitrosyl iron compounds (DNICs). The iron atom is tetra-hedrally coordinated by two phosphane ligands and two NO groups with Fe-N-O bond angles of 178.76 (15) and 177.67 (14)°. ...[more]

PMID: 21522902

Similar Datasets

Dinitro-sylbis[tris-(4-fluoro-phen-yl)phosphane]iron chloro-form monosolvate.

Project description:The title compound, [Fe(NO)(2)(C(18)H(12)F(3)P)(2)]·CHCl(3), belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as 'dinitrosyl iron compounds' (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, (Fe(NO)(2)L(2), with L = P(C(6)H(4)-p-F)(3). The structure includes one metal complex mol-ecule and one chloro-form solvent mol-ecule. The iron atom is tetra-hedrally coordinated with two phosphane ligands and with two NO groups with Fe-N-O angles of 178.1 (2) and 177.0 (2)°.

| S-EPMC3051982 | biostudies-literature

Dinitro-sylbis[tris-(4-methyl-phen-yl)phosphane]iron.

Project description:The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as 'dinitrosyl iron compounds' (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2)L(2)], with L = P(C(6)H(4)-p-CH(3))(3). There are two crystallographically independent but chemically equal mol-ecules per asymmetric unit. The iron atom in each mol-ecule is tetra-hedrally coordinated by two phosphane ligands and two NO groups, with Fe-N-O angles in the range 173.84?(15)-179.31?(16)°.

| S-EPMC3052133 | biostudies-literature

trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Project description:The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27?(2)° and Rh-P bond lengths of 2.3127?(4) and 2.3219?(4)?Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675?(15)°.

| S-EPMC3009219 | biostudies-literature

cis-Dichloridobis[tris-(4-chloro-phen-yl)phosphane-?P]platinum(II) acetonitrile monosolvate.

Project description:The title compound, [PtCl(2)(C(18)H(12)Cl(3)P)(2)]·C(2)H(3)N, packs as monomeric units with a square-planar geometry around the Pt(II) atom. The two tris-(4-chloro-phen-yl)phosphane ligands are coordinated in a cis orientation, with P-Pt-P and Cl-Pt-Cl angles of 99.36?(2) and 88.02?(2)°, respectively. In the crystal, C-H?N inter-actions are observed between the phenyl rings and the acetonitrile solvent mol-ecules.

| S-EPMC3435633 | biostudies-literature

Tris(naphthalen-1-yl)phosphane chloro-form hemisolvate.

Project description:The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris-(naphthalen-1-yl)phosphane. The solvent mol-ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H?Cl and C-H?? inter-actions are observed.

| S-EPMC3589056 | biostudies-literature

(Nitrato-?O)tris-[tris-(4-fluoro-phen-yl)phosphane-?P]copper(I).

Project description:In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra-molecular ?-? inter-action [centroid-centroid distance = 3.6113?(11)?Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H?F and C-H?O inter-actions with distances in the range 2.51-2.60?Å, resulting in a tight head-to-tail packing.

| S-EPMC3515141 | biostudies-literature

(2-Chloro-3,5-dinitro-phen-yl)(piperidin-1-yl)methanone.

Project description:In the title compound, C(12)H(12)ClN(3)O(5), the piperidine ring adopts a chair conformation. One of the nitro groups is almost coplanar with the aromatic ring [O-N-C-C = -1.4?(2)°], whereas the other one is significantly twisted out of the ring plane [O-N-C-C = 34.7?(2)°]. The crystal packing is stabilized by inter-molecular ?-? stacking inter-actions with centroid-centroid distances of 3.579?(3)?Å.

| S-EPMC3089352 | biostudies-literature

(E)-1-[1-(2-Chloro-phen-yl)ethyl-idene]-2-(2,4-dinitro-phen-yl)hydrazine.

Project description:The title mol-ecule, C(14)H(11)ClN(4)O(4), is in an E configuration and is twisted with the dihedral angle between the two benzene rings being 38.48?(8)°. The ethyl-idenehydrazine plane makes dihedral angles of 6.03?(10) and 44.04?(11)°, respectively, with the dinitro- and chloro-substituted benzene rings. The two nitro groups are essentially coplanar with the bound benzene ring, making dihedral angles of 0.9?(2) and 1.65?(18)°. An intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by a weak C-H?O inter-action into a chain along the c axis. The chains are further stacked along the b axis by a ?-? inter-action with a centroid-centroid distance of 3.6088?(10)?Å.

| S-EPMC3239123 | biostudies-literature

trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50?(9), 75.51?(10) and 80.63?(10)° with each other, while in the other ligand these angles are 51.92?(10), 78.56?(11) and 86.80?(10)°. C-H?O and C-H?F inter-actions link the mol-ecules into a three-dimensional network. Each of the F atoms is disordered over two positions with refined occupancies of 0.944?(3):0.056?(3), 0.702?(4):0.298?(4), 0.829?(4):0.171?(4), 0.567?(4):0.433?(4), 0.545?(4):0.455?(4) and 0.920?(4):0.080?(4).

| S-EPMC3238589 | biostudies-literature

(Acetyl-acetonato-?(2)O,O')carbon-yl[tris-(4-chloro-phen-yl)phosphane-?P]rhodium(I).

Project description:The title compound, [Rh(C(5)H(7)O(2))(C(18)H(12)Cl(3)P)(CO)], contains the bidentate acetyl-acetonate ligand coordinated to the Rh(I) atom, forming a chelate ring [Rh-O = 2.0327?(15) and 2.0613?(14)?Å]. The Rh(I) atom is additionally coordinated by one P [Rh-P = 2.2281?(6)?Å] and one carbonyl C [Rh-C = 1.812?(2)?Å] atom, resulting in a slightly distorted square-planar geometry. The mol-ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.

| S-EPMC3343893 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data