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Dinitro-sylbis[tris-(4-chloro-phen-yl)phosphane]iron.

ABSTRACT: The title dinitrosyl iron diphosphane complex, [Fe(NO)(2)(C(18)H(12)Cl(3)P)(2)] or Fe(NO)(2)L(2) [L = P(C(6)H(4)-p-Cl)(3)] belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as dinitrosyl iron compounds (DNICs). The iron atom is tetra-hedrally coordinated by two phosphane ligands and two NO groups with Fe-N-O bond angles of 178.76?(15) and 177.67?(14)°.

SUBMITTER: Jones MW

PROVIDER: S-EPMC3051485 | biostudies-other | 2011 Jan

REPOSITORIES: biostudies-other

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Dinitro-sylbis[tris-(4-chloro-phen-yl)phosphane]iron.

Jones Myron W MW Powell Douglas R DR Richter-Addo George B GB

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

The title dinitrosyl iron diphosphane complex, [Fe(NO)(2)(C(18)H(12)Cl(3)P)(2)] or Fe(NO)(2)L(2) [L = P(C(6)H(4)-p-Cl)(3)] belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as dinitrosyl iron compounds (DNICs). The iron atom is tetra-hedrally coordinated by two phosphane ligands and two NO groups with Fe-N-O bond angles of 178.76 (15) and 177.67 (14)°. ...[more]

PMID: 21522902

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Dinitro-sylbis[tris-(4-fluoro-phen-yl)phosphane]iron chloro-form monosolvate.

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trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).

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