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Trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

ABSTRACT: The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27?(2)° and Rh-P bond lengths of 2.3127?(4) and 2.3219?(4)?Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675?(15)°.

SUBMITTER: Burgoyne AR

PROVIDER: S-EPMC3009219 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Burgoyne Andrew R AR Meijboom Reinout R Muller Alfred A Omondi Bernard O BO

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°. ...[more]

PMID: 21588819

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