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Dinitro-sylbis[tris-(4-fluoro-phen-yl)phosphane]iron chloro-form monosolvate.

ABSTRACT: The title compound, [Fe(NO)(2)(C(18)H(12)F(3)P)(2)]·CHCl(3), belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as 'dinitrosyl iron compounds' (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, (Fe(NO)(2)L(2), with L = P(C(6)H(4)-p-F)(3). The structure includes one metal complex mol-ecule and one chloro-form solvent mol-ecule. The iron atom is tetra-hedrally coordinated with two phosphane ligands and with two NO groups with Fe-N-O angles of 178.1 (2) and 177.0 (2)°.

SUBMITTER: Jones MW

PROVIDER: S-EPMC3051982 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Dinitro-sylbis[tris-(4-chloro-phen-yl)phosphane]iron.

Project description:The title dinitrosyl iron diphosphane complex, [Fe(NO)(2)(C(18)H(12)Cl(3)P)(2)] or Fe(NO)(2)L(2) [L = P(C(6)H(4)-p-Cl)(3)] belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as dinitrosyl iron compounds (DNICs). The iron atom is tetra-hedrally coordinated by two phosphane ligands and two NO groups with Fe-N-O bond angles of 178.76 (15) and 177.67 (14)°.

| S-EPMC3051485 | biostudies-literature

Dinitro-sylbis[tris-(4-methyl-phen-yl)phosphane]iron.

Project description:The title compound, [Fe(NO)(2)(C(21)H(21)P)(2)], belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as 'dinitrosyl iron compounds' (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, [Fe(NO)(2)L(2)], with L = P(C(6)H(4)-p-CH(3))(3). There are two crystallographically independent but chemically equal mol-ecules per asymmetric unit. The iron atom in each mol-ecule is tetra-hedrally coordinated by two phosphane ligands and two NO groups, with Fe-N-O angles in the range 173.84 (15)-179.31 (16)°.

| S-EPMC3052133 | biostudies-literature

trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Project description:The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27?(2)° and Rh-P bond lengths of 2.3127?(4) and 2.3219?(4)?Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675?(15)°.

| S-EPMC3009219 | biostudies-literature

cis-Dichloridobis[tris-(4-chloro-phen-yl)phosphane-κP]platinum(II) acetonitrile monosolvate.

Project description:The title compound, [PtCl(2)(C(18)H(12)Cl(3)P)(2)]·C(2)H(3)N, packs as monomeric units with a square-planar geometry around the Pt(II) atom. The two tris-(4-chloro-phen-yl)phosphane ligands are coordinated in a cis orientation, with P-Pt-P and Cl-Pt-Cl angles of 99.36 (2) and 88.02 (2)°, respectively. In the crystal, C-H⋯N inter-actions are observed between the phenyl rings and the acetonitrile solvent mol-ecules.

| S-EPMC3435633 | biostudies-literature

Tris(naphthalen-1-yl)phosphane chloro-form hemisolvate.

Project description:The title compound, P(C10H7)3·0.5CHCl3, was isolated after the unsuccessful reaction of KSeCN and tris-(naphthalen-1-yl)phosphane. The solvent mol-ecule is disordered about an inversion center. The effective cone angle of the phosphine is 203°. In the crystal, weak C-H⋯Cl and C-H⋯π inter-actions are observed.

| S-EPMC3589056 | biostudies-literature

(Nitrato-κO)tris-[tris-(4-fluoro-phen-yl)phosphane-κP]copper(I).

Project description:In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra-molecular π-π inter-action [centroid-centroid distance = 3.6113 (11) Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H⋯F and C-H⋯O inter-actions with distances in the range 2.51-2.60 Å, resulting in a tight head-to-tail packing.

| S-EPMC3515141 | biostudies-literature

2-Vinyl-pyridine-tris-(penta-fluoro-phen-yl)borane hexane monosolvate.

Project description:The title compound, C(7)H(7)N·B(C(6)F(5))(3)·C(6)H(14), was obtained by the stoichiometric reaction of 2-vinyl-pyridine and tris-(penta-fluoro-phen-yl)borane in toluene. The formed adduct exhibits a restricted rotation along the B-N bond resulting in an asymmetry, which can be also observed in the (19)F NMR spectra. The B-N distance is equivalent to the distances found for 2-methyl-pyridine and 2-ethyl-pyridine B(C(6)F(5))(3) adducts. For the final refinement, the contributions of disordered solvent mol-ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194-201; Spek (2009). Acta Cryst. D65, 148-155].

| S-EPMC3344187 | biostudies-literature

trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50?(9), 75.51?(10) and 80.63?(10)° with each other, while in the other ligand these angles are 51.92?(10), 78.56?(11) and 86.80?(10)°. C-H?O and C-H?F inter-actions link the mol-ecules into a three-dimensional network. Each of the F atoms is disordered over two positions with refined occupancies of 0.944?(3):0.056?(3), 0.702?(4):0.298?(4), 0.829?(4):0.171?(4), 0.567?(4):0.433?(4), 0.545?(4):0.455?(4) and 0.920?(4):0.080?(4).

| S-EPMC3238589 | biostudies-literature

trans-Tetra-carbonyl-bis-[tris-(4-fluoro-phen-yl)phosphane-κP]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes that are trans to each other. The Cr atom and two carbonyl groups are on a twofold axis. The benzene rings attached to the phospho-rus atom make dihedral angles of 80.32 (5), 52.91 (5) and 83.80 (5)° with each other. In the crystal, C-H⋯O and C-H⋯F inter-molecular inter-actions form an infinite three-dimensional network.

| S-EPMC3200925 | biostudies-literature

trans-Dibromidobis(triphenyl-phosphane)platinum(II) chloro-form monosolvate.

Project description:Both the platininum complex and the solvent mol-ecule of the title compound, [PtBr(2)(C(18)H(15)P)(2)]·CHCl(3), are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl(3) mol-ecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.

| S-EPMC3120480 | biostudies-literature

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