Browse
Submit Data
Databases
API
Help

Dataset Information

9 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[?-2-(4-Hy-droxy-phen-yl)acetato]-?O:O,O';?O,O':O'-bis-{aqua-(4,4'-bi-pyridine-?N)bis-[2-(4-hy-droxy-phen-yl)acetato-?O,O']holmium(III)} mono-hydrate.

ABSTRACT: In the title dinuclear complex, [Ho(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, each of the two independent Ho(III) ions is coordinated by eight O atoms from four 4-hy-droxy-phenyl-acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal-prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O-H?O and O-H?N hydrogen bonds link the mol-ecules into a three-dimensional network.

SUBMITTER: Liu JL

PROVIDER: S-EPMC3051499 | biostudies-other | 2011

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

[μ-2-(4-Hy-droxy-phen-yl)acetato]-κO:O,O';κO,O':O'-bis-{aqua-(4,4'-bi-pyridine-κN)bis-[2-(4-hy-droxy-phen-yl)acetato-κO,O']holmium(III)} mono-hydrate.

Liu Jia-Lu JL Liu Jian-Feng JF Zhao Guo-Liang GL

Acta crystallographica. Section E, Structure reports online 20110115 Pt 2

In the title dinuclear complex, [Ho(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, each of the two independent Ho(III) ions is coordinated by eight O atoms from four 4-hy-droxy-phenyl-acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal-prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O-H⋯O and O-H⋯N hydrogen bonds link the mol-ecules ...[more]

PMID: 21522861

Similar Datasets

Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bipyridine-?N)bis-[2-(4-hy-droxy-phen-yl)acetato-?O,O']thulium(III)} mono-hydrate.

Project description:In the title dinuclear complex, [Tm(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Tm(III) atoms are coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine ligand in a distorted tricapped trigonal-prismatic geometry. While four of the HPAA ligands coordinate to just one Tm atom, the remaining two HPAA ligands bridge the two Tm atoms. In the crystal, O-H?O and O-H?N hydrogen bonds link the mol-ecules into a three-dimensional network.

| S-EPMC3009223 | biostudies-literature

Bis[2-(4-hy-droxy-phen-yl)acetato-?O]bis-(1,10-phenanthroline-?N,N')cadmium penta-hydrate.

Project description:In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hy-droxy-phen-yl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal-prismatic geometry. O-H?O hydrogen bonds between water mol-ecules and the complex mol-ecules result in the formation of a three-dimensional network. Four water mol-ecules act as single acceptors and double donors while the fifth water mol-ecule is involved as a single acceptor and single donor in an O-H?O inter-action and as a donor in an O-H?? inter-action.

| S-EPMC3051641 | biostudies-literature

Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bi-pyridine-?N)[2-(4-hy-droxy-phen-yl)acetato-?O,O']erbium(III)} monohydrate.

Project description:The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hy-droxy-phen-yl)acetate (PAA) anions, two 4,4'-bipyridine (bipy) mol-ecules, two coordinated water mol-ecules and one solvent water mol-ecule. The central Er(III) atoms are nine-coordinated. The coordination environment includes six O atoms from three PAA anions, one bridging O atom from a PAA anion, one O atom from a water mol-ecule and an N atom from a bipy ligand in a distorted tricapped trigonal-prismatic geometry. The occurrence of numerous O-H?O and O-H?N hydrogen bonds involving coordinated and noncoordinated water as well as bipy groups builds up an intricate three-dimensional network.

| S-EPMC3011679 | biostudies-literature

catena-Poly[[[diaqua-(nitrato-?O,O')cerium(III)]-bis-[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'] mono-hydrate].

Project description:In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water mol-ecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, inter-molecular O-H?O hydrogen bonds form a three-dimensional network which consolidates the packing.

| S-EPMC3011495 | biostudies-literature

Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bipyridine-?N)bis-[2-(4-hy-droxy-phen-yl)acetato-?O,O']ytterbium(III)} monohydrate.

Project description:In the title dinuclear complex, [Yb(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Yb(III) atoms are coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal-prismatic geometry. Whereas four HPAA ligands coordinate to just two Yb(III) atoms, the remaining two ligands bridge the two Yb(III) atoms. In the crystal structure, O-H?O and O-H?N hydrogen bonds link the mol-ecules into a three-dimensional network.

| S-EPMC3009163 | biostudies-literature

Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bipyridine-?N)bis-[2-(4-hy-droxy-phen-yl)acetato-?O,O']dysprosium(III)} monohydrate.

Project description:In the title dinuclear complex, [Dy(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Dy(III) atoms are coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal prismatic geometry. Whereas four HPAA ligands coordinate to just two Dy(III) atoms, the remaining two ligands bridge the two Dy(III) atoms. In the crystal, O-H?O and O-H?N hydrogen bonds link the mol-ecules into a three-dimensional network.

| S-EPMC3011410 | biostudies-literature

Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bipyridine-?N)[2-(4-hy-droxy-phen-yl)acetato-?O,O']samarium(III)} monohydrate.

Project description:The dinuclear title complex, [Sm(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Sm(III) atoms, six deprotonated p-hy-droxy-phenyl-acetic acid (PAA) mol-ecules, two 4,4'-bipyridine (bipy) mol-ecules, two coordinated water mol-ecules and one solvent water molecule. Each Sm(III)ion is nine-coordinated by seven O atoms from four PAA ligands, one water O atom and one N atom from a bipy ligand in a distorted geometry. The PAA ligands are coordinated to the Sm(III) ion in bridging and bridging tridentate modes. The asymmetric unit also contains one uncoordinated water mol-ecule. The occurrence of numerous O-H?O and O-H?N hydrogen bonds involving coordinated and non-coordinated water mol-ecules builds up an intricate three-dimensional network.

| S-EPMC3011563 | biostudies-literature

Bis(2-hy-droxy-phen-yl)methanone.

Project description:In the title compound, C(13)H(10)O(3), a benzophenone derivative, the least-squares planes defined by the C atoms of the 2-hy-droxy-phenyl rings inter-sect at an angle of 45.49?(3)°. The substituents on the aromatic systems are both orientated towards the central O atom. Intra- as well as inter-molecular O-H?O hydrogen bonds are observed, the latter giving rise to the formation of centrosymmetric dimers. The closest centroid-centroid distance between two ?-systems is 3.7934?(7)?Å.

| S-EPMC3212291 | biostudies-literature

catena-Poly[[{diaqua-[2-(4-hy-droxy-phen-yl)acetato-?O,O']cerium(III)}-bis-[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'] 4,4'-bipyridine disolvate monohydrate].

Project description:In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and two water mol-ecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bridge two Ce(III) ions. The 4,4'-bipyridine mol-ecule and one water mol-ecule are not coordinated to Ce. In the crystal, O-H?O and O-H?N hydrogen bonds link mol-ecules into a three-dimensional network.

| S-EPMC3011412 | biostudies-literature

Bis{6-meth-oxy-2-[(4-methyl-phen-yl)iminiometh-yl]phenolate-?O,O'}tris-(nitrato-?O,O')holmium(III) mono-hydrate.

Project description:The crystal structure of the title compound, [Ho(NO(3))(3)(C(15)H(15)NO(2))(2)]·H(2)O, contains two Schiff base 6-meth-oxy-2-[(4-methyl-phen-yl)iminiometh-yl]phenolate (L) ligands, three independent nitrate ions that chelate to the Ho(III) ion with O atoms and a hydrate water mol-ecule. The coordination environment of the Ho(III) ion is ten-coordinate. The L ligands chelate with a strong Ho-O(phenolate) bond and weaker Ho-O(meth-oxy) contacts. The latter can be inter-preted as the apices of the bicapped square-anti-prismatic [HoO(10)] polyhedron. Inter-molecular N-H?O hydrogen bonds occur. Intra-molecular O-H?O inter-actions link the complex mol-ecules and uncoordinated water mol-ecules.

| S-EPMC3011490 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data