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Catena-Poly[[bis(pyridine)-lead(II)]bis(?-penta-fluoro-benzene-thiol-ato)].

ABSTRACT: The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ?-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter-molecular Pb?S inter-actions [3.618?(4) and 3.614?(4)?Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

SUBMITTER: Appleton SE

PROVIDER: S-EPMC3120355 | biostudies-other | 2011 Jun

REPOSITORIES: biostudies-other

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catena-Poly[[bis(pyridine)-lead(II)]bis(μ-penta-fluoro-benzene-thiol-ato)].

Appleton Sarah E SE Briand Glen G GG Decken Andreas A Smith Anita S AS

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The title compound, [Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2)](n), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter-molecular Pb⋯S inter-actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010]. ...[more]

PMID: 21754614

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