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Bis[4-bromo-2-(ethyl-imino-meth-yl)phenolato-?N,O]nickel(II).

ABSTRACT: In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl-imino-meth-yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C-H?Br contacts (H?Br = 3.009?Å).

SUBMITTER: Chen FL

PROVIDER: S-EPMC3151835 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Bis[4-bromo-2-(ethyl-imino-meth-yl)phenolato-κN,O]nickel(II).

Chen Fu Li FL Zhang Shu Hua SH Guo Jing Jing JJ Zhang Yi Dong YD Feng Chao C

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl-imino-meth-yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C-H⋯Br contacts (H⋯Br = 3.009 Å). ...[more]

PMID: 21836857

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