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6-[(4-Hy-droxy-phen-yl)diazenyl]-1,10-phenanthrolin-1-ium chloride monohydrate.

ABSTRACT: In the cation of the title mol-ecular salt, C(18)H(13)N(4)O(+)·Cl(-)·H(2)O, the dihedral angle between the mean planes of the 1,10-phenanthroline system and the phenol ring is 14.40?(19)°. The crystal packing is stabilized by O-H?O hydrogen bonds, weak N-H?Cl and O-H?Cl inter-molecular inter-actions and ?-? stacking inter-actions [centroid-centroid distance = 3.6944?(13) and 3.9702?(12)?Å].

SUBMITTER: Hazeen A

PROVIDER: S-EPMC3238824 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

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6-[(4-Hy-droxy-phen-yl)diazenyl]-1,10-phenanthrolin-1-ium chloride monohydrate.

Hazeen Akram A Zhang Yan Y Mao Minchong M Wheeler Kraig A KA McGuire Mark E ME

Acta crystallographica. Section E, Structure reports online 20111102 Pt 12

In the cation of the title mol-ecular salt, C(18)H(13)N(4)O(+)·Cl(-)·H(2)O, the dihedral angle between the mean planes of the 1,10-phenanthroline system and the phenol ring is 14.40 (19)°. The crystal packing is stabilized by O-H⋯O hydrogen bonds, weak N-H⋯Cl and O-H⋯Cl inter-molecular inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.6944 (13) and 3.9702 (12) Å]. ...[more]

PMID: 22199677

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