Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N-(3,5-Dichloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

ABSTRACT: In the title compound, C(18)H(13)Cl(2)NO, the naphthalene ring system [maximum deviation = 0.038?(4)?Å] and the benzene ring form dihedral angles of 69.5?(2) and 37.2?(2)°, respectively, with the essentially planar acetamide unit [maximum deviation = 0.004?(4)?Å]. The naphthalene ring system forms a dihedral angle of 52.36?(18)° with the benzene ring. In the crystal, mol-ecules are linked via inter-molecular N-H?O hydrogen bonds, forming chains along [001].

SUBMITTER: Fun HK

PROVIDER: S-EPMC3247353 | biostudies-other | 2011 Nov

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

N-(3,5-Dichloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Fun Hoong-Kun HK Quah Ching Kheng CK Narayana B B Nayak Prakash S PS Sarojini B K BK

Acta crystallographica. Section E, Structure reports online 20111012 Pt 11

In the title compound, C(18)H(13)Cl(2)NO, the naphthalene ring system [maximum deviation = 0.038 (4) Å] and the benzene ring form dihedral angles of 69.5 (2) and 37.2 (2)°, respectively, with the essentially planar acetamide unit [maximum deviation = 0.004 (4) Å]. The naphthalene ring system forms a dihedral angle of 52.36 (18)° with the benzene ring. In the crystal, mol-ecules are linked via inter-molecular N-H⋯O hydrogen bonds, forming chains along [001]. ...[more]

PMID: 22219971

Similar Datasets

N-(2,6-Dichloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(13)Cl(2)NO, the naphthalene ring system and the benzene ring form dihedral angles of 74.73 (13) and 62.53 (16)°, respectively, with the acetamide grouping [maximum deviation = 0.005 (3) Å]. The naphthalene ring system forms a dihedral angle of 75.14 (13)° with the benzene ring. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming C(4) chains propagating in [010]. The O atom also accepts two C-H⋯O inter-actions.

| S-EPMC3344513 | biostudies-literature

2-Chloro-N-(3,5-dichloro-phen-yl)acetamide.

Project description:The structure of the title compound, C(8)H(6)Cl(3)NO, is closely related to that of N-(3,5-dichloro-phen-yl)acetamide and other amides. The mol-ecular skeleton is essentially planar. The mol-ecules in the crystal structure are stabilized by N-H⋯O and N-H⋯Cl inter-molecular hydrogen bonds running along the a axis.

| S-EPMC2960189 | biostudies-literature

2,2-Dichloro-N-(3,5-dimethyl-phen-yl)-acetamide.

Project description:The structure of the title compound, C(10)H(11)Cl(2)NO, resembles those of 2,2-dichloro-N-phenyl-acetamide, 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, 2,2-dichloro-N-(3-methyl-phen-yl)-acetamide, 2,2-dichloro-N-(4-methyl-phen-yl)acetamide, N-(3,5-dimethyl-phen-yl)acetamide and other acetanilides, with similar bond parameters. The mol-ecules in the title compound are linked into infinite chains through N-H⋯O and C-H⋯O hydrogen bonding.

| S-EPMC2915270 | biostudies-literature

N-{2-[2-(2,6-Dichloro-3,5-dimethoxy-phen-yl)ethen-yl]phen-yl}acetamide.

Project description:The C=C double bond in the title substituted stilbene, C(18)H(17)Cl(2)NO(3), has a trans arrangement of the aryl substit-uents. The aromatic ring of the 2-acetyl-amino-phenyl substit-uent is twisted by 39.9?(3)° with respect to the central C-C=C-C unit and that of the 2,6-dichloro-3,5-dimethoxy-phenyl substitutent is twisted by 42.7?(3)°.

| S-EPMC2968122 | biostudies-literature

2,2-Dichloro-N-(2,5-dichloro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the title compound, C(8)H(5)Cl(4)NO, is syn to the 2-chloro substituent and anti to the 5-chloro substituent in the aromatic ring. The bond parameters are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. In the crystal structure, the mol-ecules are linked into chains through N-H?O hydrogen bonding.

| S-EPMC2915043 | biostudies-literature

N-(3,5-Dichloro-phen-yl)benzamide.

Project description:The conformation of the H-N-C=O unit in the title compound, C(13)H(9)Cl(2)NO, is trans, similar to the conformation observed in N-(3-chloro-phen-yl)benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(2,4-dichloro-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and N-(3,4-dichloro-phen-yl)benz-amide. The amide group makes dihedral angles of 14.3?(8) and 44.4?(4)° with the benzoyl and aniline rings, respectively, while the benzoyl and aniline rings form a dihedral angle of 58.3?(1)°. The mol-ecules are linked by N-H?O hydrogen bonds into infinite chains running along the c axis.

| S-EPMC2961786 | biostudies-literature

N-(4-Chloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(14)ClNO, the naphthalene ring system [maximum deviation = 0.014 (9) Å] forms a dihedral angle of 74.8 (2)° with the benzene ring. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds into chains propagating along [010].

| S-EPMC3414919 | biostudies-literature

N-(2-Bromo-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(14)BrNO, the naphthalene ring system [maximum deviation = 0.015 (3) Å] forms a dihedral angle of 67.70 (10)° with the benzene ring. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into C(4) chains propagating in [100]. A C-H⋯O inter-action reinforces the chain connectivity, generating an R(2) (1)(6) loop.

| S-EPMC3435683 | biostudies-literature

2,4-Dichloro-N-(3,5-dichloro-phen-yl)benzene-sulfonamide.

Project description:In the title compound, C(12)H(7)Cl(4)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the ortho-Cl atom of the sulfonyl-benzene ring and one of the meta-Cl atoms of the aniline ring. The C-SO(2)-NH-C torsion angle is -93.9?(2)°. The benzene rings are tilted relative to each other by 61.9?(1)°. The crystal structure features inversion-related dimers linked by pairs of N-H?O hydrogen bonds.

| S-EPMC3247380 | biostudies-literature

2,2-Dichloro-N-(3,4-dimethyl-phen-yl)acetamide.

Project description:In the title compound, C(10)H(11)Cl(2)NO, the N-H bond is syn to the 3-methyl substituent in the aromatic ring, similar to that observed in N-(3,4-dimethyl-phen-yl)acetamide and to the 3-chloro substituent in 2,2-dichloro-N-(3,4-dichloro-phen-yl)acetamide, and contrasting with the anti conformation observed for the 3-methyl substituent in 2,2,2-trichloro-N-(3,4-dimethyl-phen-yl)acetamide. On the other hand, it is anti to the C=O bond. An inter-molecular N-H?O hydrogen bond links mol-ecules into infinite chains along the b axis.

| S-EPMC2969347 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data