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Chlorido{2-[(dimethyl-amino)-meth-yl]phenyl-?N,C}tellurium.

ABSTRACT: The crystal structure of the title compound, C(9)H(12)ClNTe, contains isolated mol-ecules with no close Te?Cl inter-molecular contacts and has the same composition as a previously published structure [Engman et al. (2004 ?). Phospho-rus Sulfur Silicon Relat. Elem.179, 285-292]. However, in this case, the compound has crystallized in a centrosymmetric space group, unlike the previously published structure which contained enanti-omerically pure chiral mol-ecules. In all other aspects, the metrical parameters are similar. The mol-ecules with a T-shaped coordination environment about the Te atom are linked into dimers by C-H?Cl inter-actions.

SUBMITTER: Rakesh P

PROVIDER: S-EPMC3254548 | biostudies-other | 2012 Jan

REPOSITORIES: biostudies-other

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Chlorido{2-[(dimethyl-amino)-meth-yl]phenyl-κN,C}tellurium.

Rakesh Prakul P Singh Harkesh B HB Butcher Ray J RJ

Acta crystallographica. Section E, Structure reports online 20111223 Pt 1

The crystal structure of the title compound, C(9)H(12)ClNTe, contains isolated mol-ecules with no close Te⋯Cl inter-molecular contacts and has the same composition as a previously published structure [Engman et al. (2004 ▶). Phospho-rus Sulfur Silicon Relat. Elem.179, 285-292]. However, in this case, the compound has crystallized in a centrosymmetric space group, unlike the previously published structure which contained enanti-omerically pure chiral mol-ecules. In all other aspects, the metrical ...[more]

PMID: 22259496

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Dibromidochlorido{2-[(dimethyl-amino)-meth-yl]phenyl-?N,C}tellurium(IV).

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