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Poly[[?(2)-1,3-bis-(imidazol-1-ylmeth-yl)benzene][?(2)-2,2'-dihy-droxy-1,1'-methyl-enebis(naphthalene-3-carboxyl-ato)]zinc].

ABSTRACT: In the title compound, [Zn(C(23)H(14)O(6))(C(14)H(14)N(4))](n), the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry. The 1,3-bis-(imidazol-1-ylmeth-yl)benzene and 2,2'-dihy-droxy-1,1'-methyl-enebis(naphthalene-3-carboxy-l-ate) ligands con-nect the Zn(II) ions alternately in different directions, forming a layered structure parallel to the ac plane. Topological analysis reveals that the whole structure is a (4,4) network. The layers are further assembled into a three-dimensional supra-molecular structure via C-H?O and C-H?? inter-actions.

SUBMITTER: Peng Y

PROVIDER: S-EPMC3274865 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Poly[[μ(2)-1,3-bis-(imidazol-1-ylmeth-yl)benzene][μ(2)-2,2'-dihy-droxy-1,1'-methyl-enebis(naphthalene-3-carboxyl-ato)]zinc].

Peng Yanqiang Y Wei Xilian X Li Dacheng D Wang Suna S

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

In the title compound, [Zn(C(23)H(14)O(6))(C(14)H(14)N(4))](n), the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry. The 1,3-bis-(imidazol-1-ylmeth-yl)benzene and 2,2'-dihy-droxy-1,1'-methyl-enebis(naphthalene-3-carboxy-l-ate) ligands con-nect the Zn(II) ions alternately in different directions, forming a layered structure parallel to the ac plane. Topological analysis reveals that the whole structure is a (4,4) network. The layers are further assembled into a three-dimension ...[more]

PMID: 22346812

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