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Aqua-[1,8-bis-(pyridin-2-yl)-3,6-dithia-octane-?N,S,S',N']copper(II) dinitrate acetonitrile monosolvate.

ABSTRACT: In the title compound, [Cu(C(16)H(20)N(2)S(2))(H(2)O)](NO(3))(2)·CH(3)CN, the Cu(II) atom displays a distorted square-pyramidal coordination, in which a water mol-ecule occupies the apical position and the basal plane is formed by two N atoms and two S atoms of a 1,8-bis-(pyridin-2-yl)-3,6-dithia-octane ligand. The crystal packing is stabilized by O-H?O and C-H?O hydrogen bonds.

SUBMITTER: Manzanera-Estrada M

PROVIDER: S-EPMC3274872 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Aqua-[1,8-bis-(pyridin-2-yl)-3,6-dithia-octane-κN,S,S',N']copper(II) dinitrate acetonitrile monosolvate.

Manzanera-Estrada Mayra M Flores-Alamo Marcos M Grevy M Jean-Michel JM Ruiz-Azuara Lena L Ortiz-Frade Luis L

Acta crystallographica. Section E, Structure reports online 20120111 Pt 2

In the title compound, [Cu(C(16)H(20)N(2)S(2))(H(2)O)](NO(3))(2)·CH(3)CN, the Cu(II) atom displays a distorted square-pyramidal coordination, in which a water mol-ecule occupies the apical position and the basal plane is formed by two N atoms and two S atoms of a 1,8-bis-(pyridin-2-yl)-3,6-dithia-octane ligand. The crystal packing is stabilized by O-H⋯O and C-H⋯O hydrogen bonds. ...[more]

PMID: 22346819

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