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(Z)-4-(3-Fluoro-phen-yl)-1-(5-nitro-2-oxo-indolin-3-yl-idene)thio-semicarbazide.

ABSTRACT: In the title compound, C(15)H(10)FN(5)O(3)S, an intra-molecular N-H?N hydrogen bond generates an S(5) ring, whereas N-H?O and C-H?S inter-actions complete S(6) ring motifs. The dihedral angle between the isatin ring system and the fluoro-benzene ring is 5.96?(6)° and the complete mol-ecule is close to planar (r.m.s. deviation for all the non-H atoms = 0.112?Å). In the crystal, mol-ecules are linked by N-H?O hydrogen bonds to form C(8) chains along the [100] direction and C-H?O inter-actions are also observed.

SUBMITTER: Pervez H

PROVIDER: S-EPMC3295458 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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(Z)-4-(3-Fluoro-phen-yl)-1-(5-nitro-2-oxo-indolin-3-yl-idene)thio-semicarbazide.

Pervez Humayun H Manzoor Nazia N Yaqub Muhammad M Tahir M Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title compound, C(15)H(10)FN(5)O(3)S, an intra-molecular N-H⋯N hydrogen bond generates an S(5) ring, whereas N-H⋯O and C-H⋯S inter-actions complete S(6) ring motifs. The dihedral angle between the isatin ring system and the fluoro-benzene ring is 5.96 (6)° and the complete mol-ecule is close to planar (r.m.s. deviation for all the non-H atoms = 0.112 Å). In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds to form C(8) chains along the [100] direction and C-H⋯O inter-actions are ...[more]

PMID: 22412569

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