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Cis-Tetra-aqua-bis-{5-[4-(1H-imidazol-1-yl-?N(3))phen-yl]tetra-zolido}manganese(II) dihydrate.

ABSTRACT: In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the Mn(2+) lies on a twofold rotation axis and is six-coordinated by two N atoms from the cis-related monodentate 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four O atoms from the coordinated water mol-ecules. The complex mol-ecules are connected via water O-H?O and O-H?N hydrogen bonds and weak ?-? stacking inter-actions between the benzene rings [minimum ring centroid separation = 3.750?(6)?Å] into a three-dimensional polymeric structure. The imidazolyl group of the ligand is partially disordered over two sets of sites with refined occupancies of 0.531?(7):0.469?(7).

SUBMITTER: Tong SW

PROVIDER: S-EPMC3343834 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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cis-Tetra-aqua-bis-{5-[4-(1H-imidazol-1-yl-κN(3))phen-yl]tetra-zolido}manganese(II) dihydrate.

Tong Shao-Wei SW Song Wen-Dong WD Miao Dong-Liang DL Li Shi-Jie SJ An Jing-Bo JB

Acta crystallographica. Section E, Structure reports online 20120317 Pt 4

In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the Mn(2+) lies on a twofold rotation axis and is six-coordinated by two N atoms from the cis-related monodentate 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four O atoms from the coordinated water mol-ecules. The complex mol-ecules are connected via water O-H⋯O and O-H⋯N hydrogen bonds and weak π-π stacking inter-actions between the benzene rings [minimum ring centroid separation = 3.750 (6) Å] into a three-dimensional pol ...[more]

PMID: 22589808

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cis-Tetra-aqua-bis-{5-[4-(1H-imidazol-1-yl-?N(3))phen-yl]tetra-zolido}manganese(II) dihydrate.

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