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Tetra-aqua-bis[4-(imidazol-1-yl-?N)benzoato]manganese(II).

ABSTRACT: In the title compound, [Mn(C(10)H(7)N(2)O(2))(2)(H(2)O)(4)], the Mn(II) atom, lying on an inversion center, has an octa-hedral environment with four coordinated water mol-ecules in the equatorial plane and two N atoms from two 4-(imidazol-1-yl)benzoate ligands at the axial sites. The complex mol-ecules are connected into a three-dimensional network by extensive hydrogen bonds between the water mol-ecules and the carboxyl-ate O atoms.

SUBMITTER: Zhu L

PROVIDER: S-EPMC2979258 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis[4-(imidazol-1-yl-κN)benzoato]manganese(II).

Zhu Lei L Wang Dabin D Xu Hongyan H

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

In the title compound, [Mn(C(10)H(7)N(2)O(2))(2)(H(2)O)(4)], the Mn(II) atom, lying on an inversion center, has an octa-hedral environment with four coordinated water mol-ecules in the equatorial plane and two N atoms from two 4-(imidazol-1-yl)benzoate ligands at the axial sites. The complex mol-ecules are connected into a three-dimensional network by extensive hydrogen bonds between the water mol-ecules and the carboxyl-ate O atoms. ...[more]

PMID: 21579010

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