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{2-[(2-Amino-cyclo-hex-yl)imino-meth-yl]phenolato}dioxidovanadium(V).

ABSTRACT: In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, mol-ecules are connected by N-H?O and N-H?(O,O) hydrogen bonds, forming a tetra-mer.

SUBMITTER: Sun XZ

PROVIDER: S-EPMC3343864 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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{2-[(2-Amino-cyclo-hex-yl)imino-meth-yl]phenolato}dioxidovanadium(V).

Sun Xin-Zhi XZ

Acta crystallographica. Section E, Structure reports online 20120324 Pt 4

In the title dioxidovanadium complex, [V(C(13)H(17)N(2)O)O(2)], the V(V) atom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, mol-ecules are connected by N-H⋯O and N-H⋯(O,O) hydrogen bonds, forming a tetra-mer. ...[more]

PMID: 22589838

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