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[(1S,2S)-2-(1-{[2-(2-Oxidobenzyl-idene-amino)-cyclo-hex-yl]imino}-eth-yl)phenolato-?O,N,N',O']copper(II).

ABSTRACT: In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo-hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89?(9)°. The crystal structure is devoid of any classical hydrogen bonds. However, inter-molecular C-H?O inter-actions are present and stabilize the structure.

SUBMITTER: Suleiman Gwaram N 

PROVIDER: S-EPMC3007062 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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[(1S,2S)-2-(1-{[2-(2-Oxidobenzyl-idene-amino)-cyclo-hex-yl]imino}-eth-yl)phenolato-κO,N,N',O']copper(II).

Suleiman Gwaram Nura N   Khaledi Hamid H   Mohd Ali Hapipah H  

Acta crystallographica. Section E, Structure reports online 20100618 Pt 7

In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo-hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, inter-molecular C-H⋯O inter-actions are present and stabilize the  ...[more]

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