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Tetra-kis(4-meth-oxy-anilinium) hexa-chloridobismuthate(III) chloride monohydrate.

ABSTRACT: In the crystal of the title compound, (C(7)H(10)NO)(4)[BiCl(6)]Cl·H(2)O, the Bi(III) cation is located on an inversion center and coordinated by six Cl(-) anions in a slightly distorted octa-hedral geometry; the uncoordinated Cl(-) anion and lattice water mol-ecule are located on a twofold rotation axis. Two independent 4-meth-oxy-anilinium cations are linked to the Bi complex, the uncoordinated Cl(-) anion and lattice water mol-ecule via N-H?Cl and N-H?O hydrogen bonds.

SUBMITTER: Liu ML

PROVIDER: S-EPMC3344373 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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Tetra-kis(4-meth-oxy-anilinium) hexa-chloridobismuthate(III) chloride monohydrate.

Liu Ming-Liang ML

Acta crystallographica. Section E, Structure reports online 20120421 Pt 5

In the crystal of the title compound, (C(7)H(10)NO)(4)[BiCl(6)]Cl·H(2)O, the Bi(III) cation is located on an inversion center and coordinated by six Cl(-) anions in a slightly distorted octa-hedral geometry; the uncoordinated Cl(-) anion and lattice water mol-ecule are located on a twofold rotation axis. Two independent 4-meth-oxy-anilinium cations are linked to the Bi complex, the uncoordinated Cl(-) anion and lattice water mol-ecule via N-H⋯Cl and N-H⋯O hydrogen bonds. ...[more]

PMID: 22590139

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