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Dichlorido[methyl 2-(quinolin-8-yl-oxy-?(2)N,O)acetate-?O]mercury(II).

ABSTRACT: In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is penta-coordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yl-oxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal-bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg?Cl inter-action, leading to a distorted octa-hedral coordination geometry around the Hg(II) ion.

SUBMITTER: Wang YH

PROVIDER: S-EPMC3393207 | biostudies-other | 2012 Jul

REPOSITORIES: biostudies-other

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Dichlorido[methyl 2-(quinolin-8-yl-oxy-κ(2)N,O)acetate-κO]mercury(II).

Wang Yu-Hong YH Zhu Xue-Hua XH Song Rui-Feng RF

Acta crystallographica. Section E, Structure reports online 20120620 Pt 7

In the neutral title complex, [HgCl(2)(C(12)H(11)NO(3))], the Hg(II) ion is penta-coordinated by two Cl atoms, one N atom and two weakly coordinating O atoms from the methyl 2-(quinolin-8-yl-oxy)acetate ligand. The coordination around the Hg(II) ion may be described as highly distorted trigonal-bipyramidal. Centrosymmetric dimers are formed by an additional weak Hg⋯Cl inter-action, leading to a distorted octa-hedral coordination geometry around the Hg(II) ion. ...[more]

PMID: 22807775

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