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Catena-Poly[[[bis-(thio-urea-?S)cadmium]-di-?-thio-cyanato-?(2)N:S;?(2)S:N] dihydrate].

ABSTRACT: The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thio-cyanate groups. Two solvent mol-ecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coordinated in a distorted octa-hedral fashion by two N and two S atoms from four thio-cyanate ligands and by two S atoms from two thio-urea mol-ecules. Weak O-H?S, N-H?O and N-H?N inter-actions reinforce the structure.

SUBMITTER: Mietlarek-Kropidlowska A 

PROVIDER: S-EPMC3414119 | biostudies-other | 2012 Aug

REPOSITORIES: biostudies-other

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catena-Poly[[[bis-(thio-urea-κS)cadmium]-di-μ-thio-cyanato-κ(2)N:S;κ(2)S:N] dihydrate].

Mietlarek-Kropidłowska Anna A   Chojnacki Jaroslaw J  

Acta crystallographica. Section E, Structure reports online 20120710 Pt 8

The title compound, {[Cd(NCS)(2)(CH(4)N(2)S)(2)]·2H(2)O}(n), forms a one-dimensional chain parallel to the a axis, caused by the presence of the bridging thio-cyanate groups. Two solvent mol-ecules per complex are present in the lattice. The Cd(II) ion is situated on an inversion centre and is coordinated in a distorted octa-hedral fashion by two N and two S atoms from four thio-cyanate ligands and by two S atoms from two thio-urea mol-ecules. Weak O-H⋯S, N-H⋯O and N-H⋯N inter-actions reinforce  ...[more]

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