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Catena-Poly[[bis-(2-chloro-pyrazine-?N (4))cadmium]-di-?-thio-cyanato-?(2) N:S;?(2) S:N].

ABSTRACT: Reaction of cadmium thio-cyanate with 2-chloro-pyrazine leads to the polymeric title compound, [Cd(NCS)2(C4H3ClN2)2] n . The Cd(II) cation, which is located on a center of inversion, is coordinated by two N-bonded and two S-bonded thio-cyanate anions and by two N-bonded 2-chloro-pyrazine ligands within a slightly distorted octa-hedron. The Cd(II) cations are linked into chains along the a axis by bridging thio-cyanate anions.

SUBMITTER: Wohlert S 

PROVIDER: S-EPMC3629477 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(2-chloro-pyrazine-κN (4))cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

Wöhlert Susanne S   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20130309 Pt 4

Reaction of cadmium thio-cyanate with 2-chloro-pyrazine leads to the polymeric title compound, [Cd(NCS)2(C4H3ClN2)2] n . The Cd(II) cation, which is located on a center of inversion, is coordinated by two N-bonded and two S-bonded thio-cyanate anions and by two N-bonded 2-chloro-pyrazine ligands within a slightly distorted octa-hedron. The Cd(II) cations are linked into chains along the a axis by bridging thio-cyanate anions. ...[more]

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