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(Pyridin-4-yl)methyl N'-(3-phenyl-allyl-idene)hydrazinecarbodithio-ate.

ABSTRACT: In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045?Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85?(9) and 10.73?(9)°], so that, overall, the mol-ecule adopts an L-shape. The conformation about each of the N=C [1.290?(3)?Å] and C=C [1.340?(3)?Å] bonds is E. Supra-molecular chains along [1-10] are stabilized by N-H?N(pyridine) hydrogen bonding and these are connected into a double layer that stacks along the c-axis direction by C-H??(pyridine) inter-actions.

SUBMITTER: Low ML 

PROVIDER: S-EPMC3569232 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other

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(Pyridin-4-yl)methyl N'-(3-phenyl-allyl-idene)hydrazinecarbodithio-ate.

Low May Lee ML   Ravoof Thahira Begum S A TB   Tahir Mohamed Ibrahim Mohamed MI   Crouse Karen A KA   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20130104 Pt 2

In the title compound, C(16)H(15)N(3)S(2), the central C(2)N(2)S(2) residue is planar (r.m.s. deviation = 0.045 Å) and the pyridyl and benzene rings are inclined and approximately coplanar to this plane, respectively [dihedral angles = 72.85 (9) and 10.73 (9)°], so that, overall, the mol-ecule adopts an L-shape. The conformation about each of the N=C [1.290 (3) Å] and C=C [1.340 (3) Å] bonds is E. Supra-molecular chains along [1-10] are stabilized by N-H⋯N(pyridine) hydrogen bonding and these ar  ...[more]

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