Browse
Submit Data
Databases
API
Help

Dataset Information

7 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis{2-[(phenyl-imino)-meth-yl]-1H-pyrrol-1-ido}palladium(II).

ABSTRACT: In the title complex, [Pd(C11H9N2)2], the Pd(II) atom is located on an inversion centre and has a square-planar coordination geometry. The phenyl substituents at the imine N atoms make a dihedral angle of 75.0?(6)° with respect to the PdN4 plane.

SUBMITTER: Imhof W

PROVIDER: S-EPMC3588802 | biostudies-other | 2012 Dec

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis{2-[(phenyl-imino)-meth-yl]-1H-pyrrol-1-ido}palladium(II).

Imhof Wolfgang W

Acta crystallographica. Section E, Structure reports online 20121130 Pt 12

In the title complex, [Pd(C11H9N2)2], the Pd(II) atom is located on an inversion centre and has a square-planar coordination geometry. The phenyl substituents at the imine N atoms make a dihedral angle of 75.0 (6)° with respect to the PdN4 plane. ...[more]

PMID: 23468767

Similar Datasets

Bis{2-[(2,4,6-trimethyl-phen-yl)imino-methyl]pyrrol-1-ido}palladium(II).

Project description:The title compound, [Pd(C(14)H(15)N(2))(2)], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central Pd(II) atom. In the crystal, three crystallographically independent complex mol-ecules are observed, one of which is located in a general position, whereas the Pd(II) atoms of the other mol-ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol-ecules show dihedral angles of 87.6?(7)/83.64?(7), 74.3?(7) and 88.3?(7)° with respect to the corresponding PdN(4) plane.

| S-EPMC3569194 | biostudies-literature

Bis{5-meth-oxy-2-[(1H-pyrrol-2-yl)methyl-imino-meth-yl]phenolato}zinc(II).

Project description:The title compound, [Zn(C(13)H(13)N(2)O(2))(2)], contains a Zn(II) centre, located on a twofold rotation axis, that is coordinated by two O atoms and two N atoms from two salicylal Schiff base mol-ecules. The crystal structure is stabilized by inter-molecular C-H?O hydrogen bonds.

| S-EPMC2970064 | biostudies-literature

Bis{2-[(1H-pyrrol-2-yl)methyl-imino-meth-yl]phenolato-κN,O}zinc(II).

Project description:In the title compound, [Zn(C(12)H(11)N(2)O)(2)], the Zn(II) atom, lying on an inversion center, is coordinated by two O atoms and two N atoms from two salicylal Schiff base ligands in a distorted square-planar geometry. A three-dimensional network is formed by inter-molecular C-H⋯N hydrogen bonds and C-H⋯π contacts.

| S-EPMC2969913 | biostudies-literature

Bis{2-[(4-chloro-phen-yl)imino-meth-yl]pyrrol-1-ido-?(2)N,N'}bis-(dimethyl-amido-?N)titanium(IV) toluene monosolvate.

Project description:The mononuclear title compound, [Ti(C(11)H(8)ClN(2))(2)(C(2)H(6)N)(2)]·C(7)H(8), was synthesized by the reaction of N-(4-chloro-phen-yl)-2-pyrrolylcarbaldimine with Ti(C(2)H(6)N)(4). The Ti(IV) ion is situated on a twofold rotation axis and displays a distorted octa-hedral geometry defined by four N atoms from two 2-[(4-chloro-phen-yl)imino-meth-yl]pyrrol-1-ide ligands and two N atoms from two dimethyl-amine ligands. The Ti-N(pyrrole) bond length [2.1041?(19)?Å] is longer than the Ti-N(dimethyl-amine) bond length [1.9013?(19)?Å]; the imine N atom exhibits the longest Ti-N bond [2.3152?(17)?Å]. The toluene solvent mol-ecule is located on a twofold rotation axis running through the C atom of the methyl group. Consequently, the H atoms of the latter are rotationally disordered. The compound contains no markable hydrogen-bonding inter-actions.

| S-EPMC3344338 | biostudies-literature

Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato}palladium(II).

Project description:In the title compound, [Pd(C(15)H(13)FNO(2))(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phen-oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the Pd(II) atom are trans to each other. The dihedral angle between the two fluoro-substituted benzene rings is 39.03?(6)°. The mol-ecular structure is stabilized by an intra-molecular C-H?O hydrogen bond. In the crystal, weak inter-molecular C-H?? inter-actions occur.

| S-EPMC3120330 | biostudies-literature

Bis[2-(3-cyano-phenyl-imino-meth-yl)phenolato]nickel(II).

Project description:In the title complex, [Ni(C(14)H(9)N(2)O)(2)], the Ni(II) atom lies on an inversion center and is coordinated by the O atom and an N atom of two Schiff base 2-(3-cyano-phenyl-imino-meth-yl)phenolate ligands in a square-planar geometry. The dihedral angle between the cyano-phenyl and phenolate rings is 47.62?(7)°.

| S-EPMC2960771 | biostudies-literature

Di-?-chlorido-bis-({9-[(2,6-diisopropyl-phen-yl)imino-meth-yl]anthracen-1-yl}palladium(II)).

Project description:The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.

| S-EPMC2961217 | biostudies-literature

Bis{2-meth-oxy-6-[(E)-(4-methyl-benz-yl)imino-meth-yl]phenolato}palladium(II) chloro-form monosolvate.

Project description:In the title complex, [Pd(C16H16NO2)2]·CHCl3, the Pd(II) cation lies on an inversion center. One Cl atom of the CHCl3 solvent mol-ecule lies on a twofold axis and the C-H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd(II) cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52?(10)° with that of the meth-oxy-phenolate ring. In the crystal, mol-ecules of the Pd(II) complex are arranged into sheets parallel to the ac plane, and the chloro-form solvent mol-ecules are located in the inter-stitial areas between the complex mol-ecules. Weak inter-molecular C-H?O and C-H?? inter-actions stabilize the packing.

| S-EPMC4158526 | biostudies-literature

Bis(?-phenyl-methano-lato)bis-({4-[(E)-(4-tert-butyl-phen-yl)(2-pyrid-ylmethyl-imino)meth-yl]-3-methyl-1-phenyl-1H-pyrazol-5-olato}zinc(II)).

Project description:In the title centrosymmetric dimeric Zn(II) complex, [Zn(2)(C(27)H(27)N(4)O)(2)(C(7)H(7)O)(2)], the Zn(II) center is coordinated by two N atoms and one O atom of the ketiminate ligand and two bridging O atoms of the benzyl-alkoxy groups. The geometry around the Zn(II) ions is distorted trigonal-bipyramidal.

| S-EPMC2977319 | biostudies-literature

Bis[2-(benzyl-imino-meth-yl)pyrrol-1-ido-?(2)N,N']bis-(dimethyl-amido-?N)titanium(IV).

Project description:The mononuclear title complex, [Ti(C(2)H(6)N)(2)(C(12)H(11)N(2))(2)], was synthesized by the reaction of 1-phenyl-N-[(pyrrol-2-yl)methyl-idene]methanamine with Ti(NMe(2))(4). The Ti(IV) atom is coordinated in a distorted octa-hedral geometry by four N atoms from two derivatized methanamine ligands and two N atoms from two dimethyl-amide ions. The dihedral angles between the pyrrole and phenyl rings in the bidentate ligands are 62.36?(9) and 78.32?(8)°. In the crystal, a weak ?-? stacking inter-action [centroid-centroid distance = 3.864?(2)?Å] involving centrosymmetrically related mol-ecules is observed.

| S-EPMC3344322 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data