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4-(Dimethyl-amino)-pyridinium tetra-chloridoferrate(III).

ABSTRACT: The title salt, (C7H11N2)[FeCl4], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004?Å) 4-(dimethyl-amino)-pyridinium cation and a tetra-hedral tetra-chloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides electrostatic inter-actions, the crystal packing features N-H?Cl and C-H?Cl hydrogen bonds between cations and anions, forming a three-dimensional network.

SUBMITTER: Khadri A

PROVIDER: S-EPMC3629474 | biostudies-other | 2013 Apr

REPOSITORIES: biostudies-other

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4-(Dimethyl-amino)-pyridinium tetra-chloridoferrate(III).

Khadri Amina A Bouchene Rafika R Bouacida Sofiane S Merazig Hocine H Roisnel Thierry T

Acta crystallographica. Section E, Structure reports online 20130309 Pt 4

The title salt, (C7H11N2)[FeCl4], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004 Å) 4-(dimethyl-amino)-pyridinium cation and a tetra-hedral tetra-chloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides electrostatic inter-actions, the crystal packing features N-H⋯Cl and C-H⋯Cl hydrogen bonds between cations and anions, forming a three-dimensional network. ...[more]

PMID: 23633992

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