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ABSTRACT:
SUBMITTER: Reiss GJ
PROVIDER: S-EPMC3647797 | biostudies-other | 2013 May
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20130410 Pt 5
The asymmetric unit of the title structure, [CoCl2(C3H11NOP)4][CoCl4]2, consists of one half of the trans-dichlorido-tetra-kis-[(di-methyl-phosphor-yl)methanaminium]cobalt(II) tetra-cation lying on an inversion center and one tetra-chloridocobaltate(II) dianion on a general position. Four O-coordinated cationic (di-methyl-phosphor-yl)methanaminium (dpmaH(+)) ligands occupy the equatorial coordination sites, whereas the chloride ligands occupy axial positions of the roughly o-cta-hedral coordinat ...[more]