Unknown

Dataset Information

0

Poly[bis-(piperazine-1,4-diium) [(?4-cyclo-hexa-phosphato)dilithium] tetra-hydrate].

ABSTRACT: In the title compound, {(C4H12N2)2[Li2(P6O18)]·4H2O} n , the phosphate ring anion, located around an inversion center, adopts a chair conformation. Adjacent P6O18 rings are linked via corner-sharing by LiO4 tetra-hedra, generating anionic porous {[Li2(P6O18)](4-)} n layers parallel to (101). The piperazine-1,4-diium cations occupy the pores and develop hydrogen bonds with the inorganic framework. An extensive network of N-H?O and O-H?O hydrogen-bonding inter-actions link the components into a three-dimensional network and additional stabilization is provided by weak C-H?O hydrogen bonds.

SUBMITTER: Ameur I 

PROVIDER: S-EPMC3684873 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Poly[bis-(piperazine-1,4-diium) [(μ4-cyclo-hexa-phosphato)dilithium] tetra-hydrate].

Ameur Iness I   Abid Sonia S   Al-Deyab Salem S SS   Rzaigui Mohamed M  

Acta crystallographica. Section E, Structure reports online 20130511 Pt 6

In the title compound, {(C4H12N2)2[Li2(P6O18)]·4H2O} n , the phosphate ring anion, located around an inversion center, adopts a chair conformation. Adjacent P6O18 rings are linked via corner-sharing by LiO4 tetra-hedra, generating anionic porous {[Li2(P6O18)](4-)} n layers parallel to (101). The piperazine-1,4-diium cations occupy the pores and develop hydrogen bonds with the inorganic framework. An extensive network of N-H⋯O and O-H⋯O hydrogen-bonding inter-actions link the components into a th  ...[more]

Similar Datasets

Unknown Tris(piperazine-1,4-diium) bis-[hexa-chloridoindate(III)] tetra-hydrate.
| S-EPMC3099932 | biostudies-literature
Unknown 1,4-Dimethyl-piperazine-1,4-diium bis-(hexa-fluoro-phosphate) dihydrate.
| S-EPMC3344619 | biostudies-literature
Unknown Bis[1-(2,3-di-methyl-phen-yl)piperazine-1,4-diium] bis-(oxonium) cyclo-hexa-phosphate dihydrate.
| S-EPMC3770409 | biostudies-literature
Unknown Piperazine-1,4-diium bis-(pyridine-2,6-dicarboxyl-ato-?O,N,O)cobaltate(II) tetra-hydrate.
| S-EPMC3151836 | biostudies-literature
Unknown Piperazine-1,4-diium bis-[tetra-chlorido-aurate(III)] dihydrate.
| S-EPMC2971124 | biostudies-literature
Unknown Bis(1-methyl-piperazine-1,4-diium) tetra-chloridocuprate(II).
| S-EPMC3152076 | biostudies-literature
Unknown Bis(1-benzyl-piperazine-1,4-diium) hexa-chloridocadmate(II) dihydrate.
| S-EPMC3007331 | biostudies-literature
Unknown Poly[1,4-bis-(4-pyridylmeth-yl)piperazine-diium [[tetra-aqua-cobaltate(II)]-?-pyromellitato-?O:O] dihydrate].
| S-EPMC2972020 | biostudies-literature
Unknown catena-Poly[[[tetra-aqua-magnesium]-trans-?-[(piperazine-1,4-diium-1,4-di-yl)bis-(methyl-ene)]di-phospho-nato] hemihydrate].
| S-EPMC3793689 | biostudies-literature
Unknown Piperazine-1,4-diium bis-(hexa-hydroxido-hepta-oxidohexa-borato-?(3) O,O',O'')cobaltate(II) hexa-hydrate.
| S-EPMC4011254 | biostudies-other