Unknown

Dataset Information

0

Catena-Poly[[[tetra-aqua-magnesium]-trans-?-[(piperazine-1,4-diium-1,4-di-yl)bis-(methyl-ene)]di-phospho-nato] hemihydrate].

ABSTRACT: The structure of the title polymer, }[Mg(C6H14N2O6P2)(H2O)4]·0.5H2O} n , is based on centrosymmetric MgO6 octahedra, which are linked by [(piperazine-1,4-diium-1,4-di-yl)bis-(methyl-ene)]di-phospho-nate ligands, forming chains parallel to [1-1-1]. These chains are connected via hydrogen bonds primarily formed between the phospho-nate groups and water mol-ecules. The latter constitute four of the corners of the MgO6 polyhedra and bind to the O atoms of the phospho-nate groups of neighbouring chains. The lattice water molecule is disordered around an inversion centre, exhibiting an occupancy of 0.25.

SUBMITTER: Schilling LH 

PROVIDER: S-EPMC3793689 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[tetra-aqua-magnesium]-trans-μ-[(piperazine-1,4-diium-1,4-di-yl)bis-(methyl-ene)]di-phospho-nato] hemihydrate].

Schilling Lars-Hendrik LH   Stock Norbert N  

Acta crystallographica. Section E, Structure reports online 20130713 Pt 8

The structure of the title polymer, }[Mg(C6H14N2O6P2)(H2O)4]·0.5H2O} n , is based on centrosymmetric MgO6 octahedra, which are linked by [(piperazine-1,4-diium-1,4-di-yl)bis-(methyl-ene)]di-phospho-nate ligands, forming chains parallel to [1-1-1]. These chains are connected via hydrogen bonds primarily formed between the phospho-nate groups and water mol-ecules. The latter constitute four of the corners of the MgO6 polyhedra and bind to the O atoms of the phospho-nate groups of neighbouring chai  ...[more]

Similar Datasets

Unknown 1-Methyl-piperazine-1,4-diium tetra-chloridozincate hemihydrate.
| S-EPMC3247527 | biostudies-literature
Unknown catena-Poly[(S)-2-methyl-piperazine-1,4-diium [[trichloridobismuthate(III)]-di-?-chlorido]].
| S-EPMC3007984 | biostudies-literature
Unknown trans-2,5-Di-methyl-piperazine-1,4-diium dinitrate.
| S-EPMC4051050 | biostudies-literature
Unknown catena-Poly[[aqua-(ethyl anilinophospho-nato-?O)sodium(I)]-di-?-aqua].
| S-EPMC2960560 | biostudies-literature
Unknown 3,3'-(Piperazine-1,4-diium-1,4-di-yl)di-propionate dihydrate.
| S-EPMC3470189 | biostudies-other
Unknown Aqua-{4,4',6,6'-tetra-fluoro-2,2'-[(piperazine-1,4-di-yl)dimethyl-ene]diphenolato}copper(II).
| S-EPMC3009016 | biostudies-literature
Unknown Piperazine-1,4-diium diacetate.
| S-EPMC3238946 | biostudies-literature
Unknown 1,4-Dimethyl-piperazine-1,4-diium dibromide dihydrate.
| S-EPMC3379296 | biostudies-literature
Unknown Piperazine-1,4-diium naphthalene-1,5-disulfonate.
| S-EPMC3201365 | biostudies-literature
Unknown 1-Methyl-piperazine-1,4-diium dipicrate.
| S-EPMC3051773 | biostudies-literature