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Tert-Butyl N-[(3R,4R)-1-(2-cyano-acet-yl)-4-methyl-piperidin-3-yl]-N-methyl-carbamate.

ABSTRACT: The piperidine ring of the title compound, C15H25N3O3, adopts a slightly distorted chair conformation with the cis substituents displaying an N-C-C-C torsion angle of 43.0?(3)°. The cyano group (plane defined by C-C-C N atoms) is bent slightly out of the plane of the amide group by 13.3?(2)°. The carbamate group is oriented at a dihedral angle of 60.3?(5)° relative to the amide group.

SUBMITTER: Gehringer M

PROVIDER: S-EPMC3685082 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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tert-Butyl N-[(3R,4R)-1-(2-cyano-acet-yl)-4-methyl-piperidin-3-yl]-N-methyl-carbamate.

Gehringer Matthias M Forster Michael M Schollmeyer Dieter D Laufer Stefan S

Acta crystallographica. Section E, Structure reports online 20130522 Pt 6

The piperidine ring of the title compound, C15H25N3O3, adopts a slightly distorted chair conformation with the cis substituents displaying an N-C-C-C torsion angle of 43.0 (3)°. The cyano group (plane defined by C-C-C N atoms) is bent slightly out of the plane of the amide group by 13.3 (2)°. The carbamate group is oriented at a dihedral angle of 60.3 (5)° relative to the amide group. ...[more]

PMID: 23795101

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