Ontology highlight
ABSTRACT:
SUBMITTER: Chegondi R
PROVIDER: S-EPMC3823554 | biostudies-other | 2013 Jun
REPOSITORIES: biostudies-other
Chegondi Rambabu R Maitra Soma S Markley Jana L JL Hanson Paul R PR
Chemistry (Weinheim an der Bergstrasse, Germany) 20130524 25
An array of examples of diastereoselective, phosphate-tether-mediated ring-closing metathesis reactions, which highlight the importance of product ring size and substrate stereochemical compatibility, as well as complexity, is reported. Studies focus primarily on the formation of bicyclo[n.3.1]phosphates, involving the coupling of C₂-symmetric dienediol subunits with a variety of simple, as well as complex, alcohol partners. ...[more]