Ontology highlight
ABSTRACT:
SUBMITTER: Xu S
PROVIDER: S-EPMC4077529 | biostudies-other | 2014
REPOSITORIES: biostudies-other
Xu Silong S Shang Jian J Zhang Junjie J Tang Yuhai Y
Beilstein journal of organic chemistry 20140430
A highly regioselective SN2' Mitsunobu reaction between Morita-Baylis-Hillman (MBH) alcohols, azodicarboxylates, and triphenylphosphine is developed, which provides an easy access to α-alkylidene-β-hydrazino acid derivatives in high yields and good stereoselectivity. This reaction represents the first direct transformation of MBH alcohols into hydrazines. ...[more]