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4-Methyl-N-[2-(pyridin-2-yl)ethyl-carbamo-thio-yl]benzamide.

ABSTRACT: In the title compound, C16H17N3OS, the dihedral angle between the planes of the benzene and pyridine rings is 71.33?(15)°. An intra-molecular N-H?O hydrogen bond is present. In the crystal, weak aromatic C-H?O hydrogen bonds link the mol-ecules into chains extending along a.

SUBMITTER: Adam F

PROVIDER: S-EPMC4158510 | biostudies-other | 2014 Aug

REPOSITORIES: biostudies-other

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4-Methyl-N-[2-(pyridin-2-yl)ethyl-carbamo-thio-yl]benzamide.

Adam Farook F Ameram Nadiah N Eltayeb Naser Eltaher NE

Acta crystallographica. Section E, Structure reports online 20140731 Pt 8

In the title compound, C16H17N3OS, the dihedral angle between the planes of the benzene and pyridine rings is 71.33 (15)°. An intra-molecular N-H⋯O hydrogen bond is present. In the crystal, weak aromatic C-H⋯O hydrogen bonds link the mol-ecules into chains extending along a. ...[more]

PMID: 25249927

Similar Datasets

Crystal structure of 2-methyl-N-[(4-methyl-pyridin-2-yl)carbamo-thio-yl]benzamide.

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Project description:In the title compound, C12H14Cl2N2O2S, the mol-ecule adopts a cis conformation with respect to the di-chloro-benzoyl group against the thiono group about the C-N bond. However, the di-chloro-benzene group and the thio-urea moiety are twisted by 75.41?(8)°. An intra-molecular N-H?O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O-H?S and O-H?O hydrogen bonds link the molecules, forming chains along the b-axis direction.

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Project description:In the title mol-ecule, C23H22N2OS, the di-phenyl-acetyl and ethyl-benzene groups adopt a trans-cis conformation, respectively, with respect to the S atom across the (S=)C-N bonds. This conformation is stabilized by an intra-molecular N-H⋯O hydrogen bond and a weak C-H⋯S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53 (15) and 73.94 (15)° with the phenyl rings. In the crystal, N-H⋯O hydrogen bonds link mol-ecules into chains along [100]. A weak C-H⋯π inter-action is also observed.

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